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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Applied physics 55 (1992), S. 317-323 
    ISSN: 1432-0630
    Schlagwort(e): 61.70.−r ; 71.55.−i ; 81.40.−z
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau , Physik
    Notizen: Abstract The central position and the infrared absorption coefficient of the 9 μm band of Si samples were measured with Fourier transform infrared spectroscopy (FTIR) at temperatures from T=77 K to 775 K. The infrared absorption coefficients were corrected by considering background absorption and free carrier absorption calculated from the increased free carrier concentration and from the resistivity determined from Hall effect measurements. We found the central position of the 9 μm band to shift to longer wavelengths with increasing temperature. The concentration [Oi] of interstitial oxygen is almost constant for T〈600 K, but decreased rapidly for T〉600 K. These results verified there are two types of thermal configurations of oxygen in silicon: The bonded Si2O configuration with a binding energy E b≈0.8 to 1.0 eV at T≈77 K to 600 K, and the Si2O configuration coexists with a quasi-free interstitial oxygen (QFIO) state for T〉600 K. The lattice potential barrier E L, which retards QFIO atoms from migrating in the lattice, is estimated to be 1.5 to 1.6 eV. From these configurations the anomalous diffusivity of oxygen in silicon can be explained quite well.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    ISSN: 1612-1112
    Schlagwort(e): Gas chromatography ; [60] Fulleropyrrolidine polysiloxane ; High temperature stationary phase
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary In this paper, a new type of [60]fulleropyrrolidine functionalized polysiloxane in which the fullerene moieties were incorporated in the main polysiloxane chain was synthesized the first time and used as a stationary phase for capillary gas chromatography. It demonstrated high column efficiency (2600–2866 plates m−1, on a 250 μm diameter column, for naphthalenek=3.1–3.2, 120 °C), a wide operational temperature range (90–360 °C) and outstanding thermostability. It can be used at 360 °C with a baseline drift of 5∼8×10−15A. Benzene homologues, aromatic hydrocarbons, polar compounds such as alcohols, esters, ketones, anilines and phthalic diesters can be seperated well on this column.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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