ISSN:
0009-2940
Schlagwort(e):
Key Words: Transition-metal ions / Bond activation, CH and CC / Tandem mass spectrometry / Amines, aliphatic
;
Chemistry
;
Inorganic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The mechanisms of the deceptively similar gas-phase chemistry of amine complexes RC(CH3)2CH2NH2/M+ (R = H, CH3 M = Fe, Co, Ni) are uncovered by the use of deuterium-labeled compounds. It is demonstrated that the details of CH/CC bond-activation reactions are strongly metal-ion-dependent, as is the product distribution itself.
Zusätzliches Material:
2 Tab.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/cber.19901230446
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