ISSN:
1588-2837
Keywords:
Unimolecular reactions
;
NO rotational distribution
;
HNO radical
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Nascent NO (X2ΠΩ=1/2, 3/2, v=0) rotational distributions following the unimolecular dissociation of HNO at 5 and 300 K have been calculated at excess energies from 5 to 500 cm−1, using the statistical adiabatic channel model on anab initio potential energy surface. The influence of the tunneling effect through the adiabatic channel barriers on the average rotational energies is investigated.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02475389
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