ISSN:
1572-8951
Keywords:
Polyoxovanadates
;
mixed valence
;
Heisenberg exchange
;
spin frustration-antiferromagnetic coupling
;
spin delocalization
;
bond valence
;
template synthesis
;
structural
;
magnetic correlations
;
irreducible tensor operators
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Oxovanadium clusters provide novel examples of large magnetic clusters, which may showin nuce the typical behavior of bulk magnetic materials. The paper reviews the magnetic properties of V15, comprising fifteen oxovanadium(IV); V14, comprising fourteen oxovanadium(IV); V3+1, comprising three localized oxovanadium(IV), six localized oxovanadium(V), and one oxovanadium(IV) delocalized over three sites; V4+2 and V4+4 which comprise four localized and two and four delocalized oxovanadium(IV), respectively. The different observed magnetic behaviors are discussed on the basis of several models of different sophistication.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00999630
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