ISSN:
0935-6304
Schlagwort(e):
GC-AED
;
High boiling PAC
;
Peak splitting in discharge tube
;
Additional make-up gas
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
Peak splitting of high molecular weight polycyclic aromatic compounds originating from the microwave plasma of an atomic emission detector (AED) coupled to a GC has been described and evaluated. The influence of the solute structure, solute concentration, and physical conditions in the AED (such as detector temperature, make-up gas flow, concentration of reagent gases and distance of column end from the plasma) have been studied. An explanation is presented for peak splitting, which is based on an insufficient solute decomposition and solute mass flow in the discharge tube. Modification of the instrument by introduction of additional make-up gas applied through the transfer line has been shown to improve peak shape and solute response.
Zusätzliches Material:
9 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/jhrc.1240170303
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