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Mechanistic studies of platinum-catalyzed hydrosilylation (1991)

Stein, J. ; Lewis, L. N. ; Smith, K. A. ; [et al.]

Springer

Journal of inorganic and organometallic polymers and materials 1 (1991), S. 325-334

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ISSN: 1572-8870

Keywords: Hydrosilylation ; addition cure ; platinum catalyst

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract The results of competitive and relative rate studies for various silicon hydrides and vinylmethylsiloxane compounds are presented. For example, the competitive reaction of bis(trimethylsiloxy)methylsilane with vinylpentamethyldisiloxane (A) and divinyltetramethyldisiloxane (B) show that B reacts preferentially; however, the relative rate of reaction is greater for A than B. Mechanistic aspects of hydrosilylation are also discussed.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00702496

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