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Solvent effect on the intramolecular hydrogen bond in 8-quinolinol N-oxide (1996)

Dziembowska, T. ; Malarski, Z. ; Szczodrowska, B.

Springer

Journal of solution chemistry 25 (1996), S. 179-189

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ISSN: 1572-8927

Keywords: Intramolecular hydrogen bond ; solvent effect ; dipole moment ; IR ; UV ; NMR

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Solvent effect on intramolecular hydrogen bond in 8-quinolinol N-oxide has been studied by IR, UV,1H NMR and13C NMR spectroscopy, dipole moment measurements and quantum-mechanical calculations. The solute-solvent interactions are of local character and they vary considerably over the range of solvent under study. The results suggest that formation complexes with solvent molecules weaken the intramolecular hydrogen bond in 8-quinolinol N-oxide.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00972688

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