ISSN:
1572-8854
Keywords:
Imidazolium
;
carbenes
;
sodium hydride
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The structure of 1,3-bis(4-methylphenyl)imidazolium chloride was determined and compared to its related imidazole-based carbene. The important structural difference is the greater N2−C2−N3 angle in the salt (109.6°) than in the carbene (101.2°). An electrochemical investigation of the salt revealed a single reduction at −2.32 V in the forward scan and two oxidations at −0.89 and −0.54 V following scan reversal.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01666725
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