ISSN:
0009-2940
Keywords:
Methylcyclopentadeienyl molybdenum(V) tetrachloride
;
Primary Phosphane ligands
;
EPR spetroscopy
;
Molybdenum
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
[Cp′MoCl4(CH3CN) (Cp′=C5H4Me) react with 2,4,6-triisopropylphenylphosphane or cyclohexylphosphane to give the phosphane complexes [Cp′MoCl4(PH2R)] [R=2,4,6-Pri3C6H2 (1)]. 1 and 2, were characterized spectroscopically (IR, MS) and by crystal structure determinations. EPR investigations in liquid and frozen solution confirmed the presence of Mo(V) species and the data were used to analyze the spin-density distribution in the first coordination sphere.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19971300621
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