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Digitale Medien

Synthesis of Isomerically Pure Organodihydrofullerenes (1993)

Hirsch, Andreas ; Grösser, Thomas ; Skiebe, Andreas ; [weitere]

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 126 (1993), S. 1061-1067

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Details

ISSN: 0009-2940

Schlagwort(e): Buckminsterfullerenes ; Organodihydrofullerenes ; Fullerene derivatives ; Chemistry ; Inorganic Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: Controlled two-step nucleophilic hydroalkylations, hydroar-ylations as well as hydrostannylations of fullerene-60 (1) and fullerene-70 (2) lead to defined organodihydrofullerenes C60HR and C70HR. NMR investigations show that only one isomer of each organodihydrofullerene with Cs symmetry is formed. In all cases the addition takes place at a double bond separating two six-membered rings of the fullerene core. In this way a variety of organodihydrofullerenes also carrying functional groups have been synthesized.

Zusätzliches Material: 6 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/cber.19931260428

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