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Hypercoordinate PII, PIII, and PIV Phosphorus Derivatives with Intramolecular Coordination by Donor Groups (1998)

Chuit, Claude ; Reyé, Catherine

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 1847-1857

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Details

ISSN: 1434-1948

Keywords: Intramolecular coordination ; Donor groups ; Phosphorus compounds ; X-ray structures ; Ligands exchange ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: This review describes phosphanes and phosphane derivatives as well as phosphenium salts in which increase in coordination number was achieved by intramolecular coordination of donor groups. This effect was established by X-ray crystal structure analysis and was also inferred from 1H-NMR studies in solution. Where possible, comparison with the corresponding silicon compounds was made.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

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