ISSN:
1434-1948
Keywords:
Peroxo complexes
;
Vanadium
;
Mass spectrometry
;
Ion-molecule reactions
;
Ab initio calculations
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Electrospray Ionization Mass Spectrometry (ESI-MS) measurements and ab initio calculations on [OV(O2)(H2O)m-(CH3OH)n]+ (m,n: 0-4) peroxo cations have been carried out. This experimental technique allowed the direct observation of the above mentioned species for the first time. The results obtained clearly indicate that the exchange reactions between water and methanol molecules, within the coordination sphere of monoperoxo-vanadium complexes, is a conceivable and fast process.
Type of Medium:
Electronic Resource
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