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Digitale Medien

Heterobimetallic and Mixed-Valence Chloro-Bridged Complexes with Orthometalated Rhodium(III) and Iridium(III) Fragments (1998)

Polborn, Kurt ; Severin, Kay

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 1187-1192

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Details

ISSN: 1434-1948

Schlagwort(e): Iridium ; Rhodium ; Chloro-bridged complexes ; Heterobimetallic complexes ; Chemistry ; General Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The synthesis and characterization of heterobimetallic and mixed-valence complexes in which orthometalated [(ppy)2MCl] (M = Rh, Ir; ppy = 2-phenylpyridine anion) and [(bzq)2RhCl] (bzq = benzo[h]quinoline anion) fragments are linked via chloro-bridges with rhodium(I), iridium(I), palladium(II), and platinum(II) fragments is reported. These complexes are formed in nearly quantitative yields by metathesis reactions from the respective homodimeric compounds. The structures of [(ppy)2Rh(μ-Cl)2Rh(cod)] (cod = η4-1,5-cyclooctadiene) and [(ppy)2Rh(μ-Cl)2Pt(PBu3)-Cl] were determined by X-ray structure analyses.

Materialart: Digitale Medien

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