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  • 1
    Electronic Resource
    Electronic Resource
    Colloidal single crystals of silica spheres in the presence of simple- and poly-electrolytes, and ionic detergents (1996)
    Springer
    Colloid & polymer science 274 (1996), S. 73-80 
    Details
    ISSN: 1435-1536
    Keywords: Colloidal crystals ; silica spheres ; electrical double layer ; single crystals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Colloidal single crystals of silica spheres (103 nm in diameter) are formed in the presence of various kinds of salts 1 simple electrolytes, i.e., sodium chloride, calcium chloride and lanthanum chloride, 2 polyelectrolytes such as 3–6 type ionen polymer (polybrene), poly-N-ethylpyridinium bromide, a copolymer ofN-benzyl pyridinium chloride andN-hexadecyl pyridinium bromide, and sodium polyethylene sulfonate, and 3 cationic and anionic detergents, hexadecyltrimethylammonium bromide and sodium dodecylsulfate. Shape and size of their single crystals, phase diagram, and the relationship between the two parameters among the critical concentration of melting, conductance and pH of the crystal-like suspensions have been studied. Colloidal single crystals ofpositively charged spheres have been formed in this study by the method of the charge reversal of spheres through the strong adsorption of cationic polyelectrolytes onto the anionic silica spheres.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00658912
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  • 2
    Electronic Resource
    Electronic Resource
    Evaluation of the dynamic properties of polymer latex particles interacting with quartz interface by evanescent wave dynamic light scattering (1998)
    Springer
    Colloid & polymer science 276 (1998), S. 349-355 
    Details
    ISSN: 1435-1536
    Keywords: Key words Evanescent wave ; dynamic light scattering ; particle-wall interaction ; colloidal particle ; time-correlation function
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract  The diffusion behavior of polymer latex particles in dispersion near the quartz interface has been estimated by evanescent wave dynamic light scattering (EVDLS) technique. The diffusion coefficient of the particles was measured as a function of the distance between the particle and interface. The apparent diffusion coefficient estimated by EVDLS was small for particles near the interface and increased upon increasing the distance from the interface, and then saturated at a certain value which is close to the value expected for free-motion. The range of the distance over which diffusion was affected by interaction with the interface depended on the added salt concentration. This means that the diffusion of the particle is influenced by an electrostatic interaction between the particle and quartz interface in addition to the hydrodynamic effect near the wall. This range was found to be more than 800 nm at 0 M salt condition but about 400 nm at 10-4 and 10-3 M salt conditions. Hence it is appropriate to say that the hydrodynamic effect reaches up to 400 nm and the electrostatic effect is longer ranged, more than 800 nm, for the system studied here. The EVDLS technique is a very powerful tool for quantitative estimations of the dynamic behavior of the particle near the interface and for estimation of the range where the wall effect is dominant. EVDLS will give us an answer to the question of “where is the ‘interface’ and where is the ‘bulk’?”.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s003960050250
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
    Fulltext
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