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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 8 (1986), S. 242-250 
    ISSN: 0392-6737
    Schlagwort(e): Liquid crystals
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Beschreibung / Inhaltsverzeichnis: Riassunto In questo lavoro sono presentati i risultati sperimentali della variazione risolta nel tempo del passo apparente di un CLC sottoposto ad una deformazione di taglio a gradino. Si mostra che la variazione relativa della lunghezza d’onda del massimo di riflessione ΔP/P 0 varia da un valore iniziale positivo (P〉P 0) ad un valore negativo (P〈P 0) dopo pochi secondi, e tende ad un valore di stturazione con ΔP/P 0〈0 all’infinito. Noi diamo una spiegazione qualitativa basata sul meccanismo dello srotolamento della struttura elicoidale e sul possibile tilt degli strati molecolari.
    Kurzfassung: Резюме В этой статье приводятся экспериментальные результаты для разрешенных во времени изменений видимого шага холестеричиой смеси после приложения ступенчатой деформации сдвига. Мы показываем, что относительное изменение длины волны максимального отражения ΔP/P 0 изменяется от начальных ппложительных знаьений (P〈P 0) до отрицательных значениь (P〈P 0 после нескольких секунд и окончательно стремится к величине насьшения с ΔP/P 0〈0 в течение длительного времени. Предлагается качественное объяснение, основанное на механизме структуры закрученной спирали и возможного изменния наклона молекул.
    Notizen: Summary In this paper we present the experimental results of time-resolved variations of the apparent pitch of a cholesteric mixture after a steplike shearing deformation is applied to it. We show that the relative variation of the wave-length of the maximum reflection ΔP/P o varies from initial positive values (P〉P 0) to negative ones (P〈P 0 after a few seconds and finally it tends to a saturation value with ΔP/P 0〈0 in a long time. A qualitative explanation based on the mechanism of the unwinding of the twisted helix structure and a possible tilt of the molecular is also given.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 10 (1996), S. 77-82 
    ISSN: 0268-2605
    Schlagwort(e): gas chromatography ; flame photometric detector ; quartz tube ; butyltin species ; water analysis ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A flame photometric detector using quartz surface-induced tin emission was designed and evaluated for quantification analysis of butyltin species. It has been demonstrated that this quartz surface-induced tin emission, centred at 390 nm, is more sensitive than the commonly used gas-phase emission at 610 nm. The dependence of detector response on quartz enclosure was studied. The operational variables such as hydrogen-air flow rate, carrier-gas flow rate and purge-gas flow rate were optimized. An analytical procedure for speciation analysis of butyltin species in water using simultaneous hydride generation with sodium borohydride and extraction into dichloromethane was established. The detection limits (defined as the signals that equal three times the deviations of the noise) were 0.3 pg of Sn for tetrabutyltin (TeBT), 5 pg of Sn for monobutyltin (MBT), 18 pg of Sn for dibutyltin (DBT) and 2 pg of Sn for tributyltin (TBT), which are approximately 10- to 30-fold better than those reported for using more commonly used gas-phase emission centred at 610 nm.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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