ISSN:
0009-2940
Keywords:
Lithium, two-coordinate
;
Lithium-nitrogen heterocycle
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
[LiN(SiMe3)Ar]2 (1, Ar = 2,6-iPr2C6H3) is prepared by the reaction of HN(SiMe3)Ar with nBuLi in n-hexane. This compound with an unusual structure contains a four-membered [LiN]2 heterocycle with two solvent-free two-coordinate Li centers. Its molecular structure represents the first solid-state X-ray analysis of an uncomplexed [LiN]2 dimer.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911241013
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