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  • 1
    Electronic Resource
    Electronic Resource
    Komplexe von Vanadium und Titan mit 2,2′-Dihydroxyazobenzen. Kristallstrukturen von 2,2′-Dihydroxyazobenzenato(2-)-oxo-methoxo-methanol-vanadium(V) und μ-Oxo-bis[2,2′-dihydroxyazobenzenato(2-)-oxo-vanadium(V)] (1994)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 620 (1994), S. 346-352 
    Details
    ISSN: 0044-2313
    Keywords: Titanium, Vanadium Complexes ; 2,2′-Dihydroxyazobenzene ; Mass Spectra ; Crystal Structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Complexes of Vanadium and Titanium with 2,2′-Dihydroxyazobenzene. Crystal Structure of 2,2′-Dihydroxybenzenato(2-)-oxo-methoxo-methanol-vanadium(V) and μ-Oxo-bis[2,2′-dihydroxyazobenzenato(2-)-oxo-vanadium(V)]By the reaction of 2,2-dihydroxyazobenzene with titanium(IV) the expected compound bis [2,2′-dihydroxybenzenato(2-)-titanium(IV)] was obtained. On the other hand in the dependence on the experimental conditions vanadium forms further compounds beside the bisligand complex. They were characterized by mass spectrometry resp. X-ray structural analysis. Crystallographic data see „Inhaltsübersicht“.
    Notes: Bei der Reaktion von 2,2′-Dihydroxyazobenzen mit Titan(IV)-isopropoxid wird erwartungsgemäß Bis[2,2′-dihydroxyazobenzenato(2-)]-titan(IV) erhalten. Vanadium bildet dagegen in Abhängigkeit von den Versuchsbedingungen neben dem Bis-Ligand-Komplex weitere Verbindungen, die massenspektrometrisch bzw. durch Röntgenkristallstrukturanalyse charakterisiert wurden.2,2′-Dihydroxyazobenzenato(2-)-oxo-methoxo-methanol-vanadium(V) Raumgruppe P21/c Z = 4, 1 561 beobachtete unabhängige Reflexe, R = 3,9%. Gitterabmessungen bei 25°C: a = 1 037,6(3) pm; b = 929,6(4) pm; c = 1 637,1(4) pm, μ = 99,66(3)°; μ-Oxo-bis[2,2′-dihydroxyazobenzenato(2-)-oxo-vanadium(V)]. Raumgruppe Pbcn, Z = 4, 1 489 beobachtete unabhängige Reflexe, R = 4,3%. Gitterabmessungen bei 25°C: a = 739,2(1) pm; b = 2 429,2(2) pm, c = 1 287,4(6) pm.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19946200224
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  • 2
    Electronic Resource
    Electronic Resource
    Template-Reaktion von Bis(acetylacetonato)-dioxo-molybdän(VI) mit Benzoylhydrazin (1994)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 620 (1994), S. 357-360 
    Details
    ISSN: 0044-2313
    Keywords: Template Reaction ; Benzolhydrazido(2-)-acetylacetonebenzoylhydrazonato(2-)-oxomolybdenum(VI) ; Acetylacetonebenzoylhydrazone ; Mass Spectra ; Crystal Structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Template Reaction of Bis(acetylacetonato)-dioxo-molybdenum(VI) with BenzoylhydrazoneBy reaction of bis(acetylacetonato)-dioxo-molybdenum(VI) with benzoylhydrazine benzoylhydrazido(2-)-acetylacetonebenzoylhydrazonato(2-)-oxo-molybdenum(VI) was formed beside another species. The compound was characterized by mass spectrometry and X-ray structural analysis. Crystallographic data see „Inhaltsübersicht“.
    Notes: Als Reaktionsprodukt der Umsetzung von Bis(acetylacetonato)-dioxo-molybdän(VI) mit Benzoylhydrazin in Gegenwart von Triphenylphosphan wurde Benzoylhydrazido-(2-)-acetylacetonbenzoylhydrazonato(2-)-oxo-molybdän(VI) neben einem weiteren Molybdänkomplex erhalten und massenspektrometrisch sowie röntgenkristallstrukturanalytisch charakterisiert. (Raumgruppe Cc, Z = 4, 2 020 beobachtete Reflexe, R = 3,7%. Gitterabmessungen bei 19°C: a = 1 188,5(2) pm, b = 2 110,2(2) pm, c = 813,2(2) pm, β = 105,77(2)°).
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19946200226
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  • 3
    Electronic Resource
    Electronic Resource
    Komplexe mit N,N,N′,N′-Tetrakis(2-hydroxybenzyl)ethylendiamin (H4tben). Kristallstruktur von Ti(tben) (1995)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 671-674 
    Details
    ISSN: 0044-2313
    Keywords: N,N,N′,N′-Tetrakis(2-hydroxybenzyl)ethylenediamine ; Complexes of Titanium(IV), Vanadium(IV), Manganese(IV), Tin(IV) ; Mass Spectra ; Mössbauer Data ; Crystal Structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Complexes with N,N,N′,N′-Tetrakis(2-hydroxybenzyl)ethylenediamine (H4tben). Crystal Structure of Ti(tben)The complexes of N,N,N′,N′-tetrakis(2-hydroxybenzyl)-ethylenediamine with titanium(IV), vanadium(IV), manganese(IV), and tin(IV) were synthesized and characterized by mass spectrometry. The Mössbauer date were evaluated for the tin compound. The molecular structure of the titanium(IV) complex was determined by X-ray structural analysis, crystallographic data see “Inhaltsübersicht”.
    Notes: Es wurden die Komplexe von N,N,N′,N′-Tetrakis(2-hydroxybenzyl)ethylendiamin mit Titan(IV), Vanadium(IV), Mangan(IV) und Zinn(IV) hergestellt und massenspektrometrisch charakterisiert. Für die Zinn-Verbindung wurden die Mössbauer-Daten ermittelt. Die Molekülstruktur des Titan(IV)-Komplexes wurde röntgenstrukturanalytisch bestimmt. N,N,N′,N′-Tetrakis(2-hydroxybenzyl)ethylendiaminato(4-)titan(IV): Raumgruppe P21/c (Nr. 14), Z = 4, 3949 Zahl der beobachteten Intensitäten, R = 0,0539, Gitterabmessung bei 20°C; a = 10,447(3) Å, b = 20,668(5) Å, c = 13,420(3) Å, b̃ = 101,93(5) Å
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19956210428
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  • 4
    Electronic Resource
    Electronic Resource
    Mangan(IV)-Komplexe mit dreizähnigen diaciden Liganden. Kristallstruktur von Acetylacetonato-salicylaldehydbenzoylhydrazonato(2-)-methanol-mangan(III)Frau Professor Brigitte Sarry zum 75. Geburtstag gewidmet (1995)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 1483-1488 
    Details
    ISSN: 0044-2313
    Keywords: Manganese(IV) Chelates, Salicylaldehyde benzoylhydrazone and salicylhydrazone ; Mass Spectra ; Crystal Structure, Acetylacetonato-salicylaldehydebenzoylhydrazonato(2-)-methanol-manganese(III) ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Manganese(IV) Complexes with Tridentate Diacidic Ligands. Crystal Structure of Acetyl-acetonato-salicylaldehydebenzoylhydrazonato(2-)-methanol-manganese(III)The manganese(IV) chelates of salicylaldehyde benzoylhydrazone and salicylaldehyde salicylhydrazone were synthesized by ligand exchange reactions using bis(acetylacetonato)manganese(II), tris(acetylacetonato)manganese(III) as well as manganese(III) acetate. The brown complexes show the expected molecular ions in the APCI mass spectra. As an intermediate compound acetyacetonato-salicylaldehydebenzoylhydrazonato(2-)-methanol-manganese(III) was isolated and characterized by X-ray structural analysis. Crystallographic data see “Inhaltsübersicht”.
    Notes: Durch Ligandenaustauschreaktion von Bis(acetylacetonato)mangan(II) und Tris(acetylacetonato)mangan(III) bzw. Mangan(III)-acetat mit Salicylaldehydbenzoylhydrazon und -salicylhydrazon wurden die Mangan(IV)-Chelate dieser Liganden dargestellt. Die braunen Verbindungen zeigen im APCI-positiv Massenspektrum die erwarteten Molekülionen. Für das Zwischenprodukt Acetylacetonato-salicylaldehydbenzoylhydrazonato(2-)-methanol-mangan(III) wurde die Kristall- und Molekülstruktur bestimmt: Gitterabmessungen bei 293 K; a = 754,3(2) pm, b = 1 027,3(6) pm, c = 1 357,4(5) pm, α = 79,64(4)°, β = 76,51(3)°, γ = 70,45(4)°, Raumgruppe P1 (Nr. 2), Z = 2, 3297 unabhängige Reflexe, R = 3,84%.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19956210908
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  • 5
    Electronic Resource
    Electronic Resource
    Oxofreie Vanadium(IV)-Komplexe mit dreizähnigen diaciden Liganden. Struktur von Bis[2,2′-dihydroxy-azobenzenato(2-)]vanadium(IV) (1995)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 23-28 
    Details
    ISSN: 0044-2313
    Keywords: Non-oxo Vanadium(IV) Complexes ; Mass Spectra ; Cyclovoltammetry ; Bis[2,2′-dihydroxy-azobenzenato(2)]vanadium(IV) ; Trigonal-prismatic Structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Non-oxo Vanadium(IV) Complexes with Tridentate Diacidic Ligands. Molecular Structure of Bis[2.2′-dihydroxy-azobenzenato(2-)]vanadium(IV)By the reaction of tris(acetylacetonato)vanadium(III) with tridentate diacidic ligands non-oxo vanadium(IV) complexes of these ligands were synthesized. The complexes were characterized by mass spectrometry. Electrochemical studies show that the complexes are reversibly oxidized or reduced. Bis[2,2′-dihydroxy-azobenzenato(2-)]vanadium(IV) has a distorted trigonal-prismatic structure. Crystallographic data see „Inhaltsübersicht“.
    Notes: Durch Reaktion von Tris(acetylacetonato)-vanadium(III) mit dreizähnigen diaciden Liganden wurden oxofreie Vanadium(IV)-Komplexe dieser Liganden dargestellt. Die Komplexe wurden massenspektrometrisch charakterisiert. Sie können elektrochemisch reversibel oxidiert und reduziert werden. Bis[2,2′-dihydroxy-azobenzenato(2-)]vanadium(IV) besitzt eine verzerrt trigonal-prismatische Struktur. Raumgruppe P21/n, Z = 4, 1 812 beobachtete unabhängige Reflexe, R = 5,9%. Gitterabmessungen bei 19°C; a = 9,973(2) pm, b = 15,435(3) pm, c = 13,763(3) pm, β = 104,79(3)°.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19956210107
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