Library

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    Separtation of metal tetrakis(p-tolyl)porphine complexes by reversed-phase high-performance liquid chromatography (1985)
    Springer
    Chromatographia 20 (1985), S. 72-74 
    Details
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Metal complexes ; Tetrakis(4-methylphenyl)porphine
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The feasibility of reversed-phase high-performance liquid chromatography for the separation of several metal complexes ofmeso-tetrakis(p-tolyl)porphine (TTP) is described. A combination of an octadecyl-bonded stationary phase with a non-aqueous polar mobile phase, such as an acetone-acetonitrile mixture, has proved effective for the separation. Thus, the TTP complexes of Mg, VO, Ni, Cu, Zn, and Pd and also TTP free acid were successfully separated in about 10min on a Li-Chrosorb RP-18 column (7μm, 250×4mm i.d.) with a 70∶30 (vol/vol) mixture of acetone and acetonitrile at a flow-rate of 1 mlmin−1.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02280599
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    High-performance thin-layer chromatography of etioporphyrin and its vanadium (IV), nickel (II) and coper (II) complexes (1985)
    Springer
    Chromatographia 20 (1985), S. 417-420 
    Details
    ISSN: 1612-1112
    Keywords: High-Performance TLC ; Metal complexes ; Etioporphyrin
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The RF values were obtained for etioporphyrin I (H2Etio) and its vanadyl, nickel and copper complexes on cellulose, silica gel, and octyl-bonded silica HPTLC plates, with various organic solvents. The mobility of these compounds tends to increase in the following order: (1) on cellulose, VOEtio 〈 H2Etio 〈 CuEtio ≤ NiEtio; (2) on silica gel, H2Etio 〈 VOEtio 〈 NiEtio ≤ CuEtio; (3) on octyl-bonded silica, CuEtio 〈 NiEtio 〈 VOEtio and the apparent mobility of H2Etio relative to metal-Etio complexes depends on the developing solvent used. Complete separation of these four Etio compounds can be accomplished on an octyl-bonded silica plate with either methanol or acetone.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02265483
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    Reversed-phase, high-performance, thin-layer chromatography of metal tetrakis (p-tolyl) porphine complexes on octadecylbonded stationary phase (1985)
    Springer
    Chromatographia 20 (1985), S. 49-52 
    Details
    ISSN: 1612-1112
    Keywords: High-performance TLC ; Metal complexes ; Tetrakis (4-methylphenyl) porphine
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The metal complexes ofmeso-tetrakis (p-tolyl) porphine (TTP) are chromatographed on octadecyl-bonded silica gel thin-layer with various organic solvents of relatively high polarity used as the eluent. The mobility of the metal-TTP complex depends on its centralmetal, increasing in the order of Cu(II)〈Pd(II)≈NI(II)〈TTP free acid〈V(IV) as vanadyl〈Zn(II)〈Mg(II), although some irregularities are found with the different developing solvents used. The concept of Hildebrand's solubility parameter is applied to the discussion of the mobility of each compound, on the solvents used as the developer. Successful separation of the TTP compounds is performed by using a mixture of acetone and acetonitrile as the developer, although the Ni- and Pd-complexes are not completely resolved.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02260487
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...