ISSN:
0009-2940
Keywords:
Grignard reagents, 1,3-di-
;
Titanocene
;
Zirconocene
;
Platinum, complexes of
;
Rhodium, complexes of
;
Iridium, complexes of
;
Metallacycles
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Five 1,8-naphthalenediyl transition metal compounds 2 were prepared by treating either 1,8-naphthalenediylmagnesium (1) or 1,8-dilithionaphthalene with the appropriate transition metal dichloride LnMCl2: LnM = Cp2Ti (2a), (PEt3)2Pt (2b), Cp* PPh3Rh (2c), Cp* PPh3Ir (2d), or Cp*2Zr (2e). The resulting metallacycles were characterized by NMR and mass spectrometry. X-ray crystal structure analyses were performed for (1,8-naphthalenediyl)titanocene (2a) and (1,8-naphthalenediyl)bis(triethylphosphane)platinum (2b). Despite the strain induced by the four-membered metal-containing rings, the naphthalene units show remarkably small distortions.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19941271006
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