ISSN:
0009-2940
Keywords:
Molybdenum(VI) compound
;
Siloxanes
;
Vanadium(V) compound
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Model Reactions to Anchor Molybdenum and Vanadium Oxides on Silica-Oxygen SurfacesThe eight-and twelve-membered ring compounds [(tBu)21-Si(O)2MoO2]2 (1) and [(tBu)2Si(O)2V(O)Cl]3 (2) have been prepared by the reaction of di-tert1-butylsilanediol or its dilithium salt with MoO2Br2 or VOCl3, respectively. Single crystal X-ray structure analyses of 1 · 2 py and 2 have been performed. Crystals of 1 · 2 py contain two molecules of 1 · 2 py and four additional molecules of pyridine in the unit cell.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19931260202
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