ISSN:
0009-2940
Schlagwort(e):
Nitroxide radical
;
Silver(I) complex
;
Chemistry
;
Inorganic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The reaction of 2,5-dihydro-4,5,5-trimethyl-2,2-di-2-pyridyl-imidazole-1-oxyl (L) with AgSbF6 gives the complex [Ag2L2]2+[SbF6-]2 which was characterized by X-ray diffraction. - The complex (a biradical) forms a four-membered ring with two Ag(I) ions and two imine nitrogen atoms of the imidazolines with a relatively short Ag - Ag distance [2.839(2) Å]. Magnetic measurements indicate that two nitroxide radicals are slightly coupled.
Zusätzliches Material:
3 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/cber.19961290515
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