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Digitale Medien

GC investigation of olefins with chemically bonded gamma-mercaptopropylsilane-copper(II) complexes (1987)

Wasiak, W.

Springer

Chromatographia 23 (1987), S. 423-426

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Details

ISSN: 1612-1112

Schlagwort(e): Gas chromatography ; Complexation ; Mercaptosilane chemically bonded phase ; Transition metal complexes ; Olefinic π-complexes

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Summary A column packing containing thiol groups chemically bonded to the silica surface was synthesized. The thiol functional groups were used as ligands capable of forming stable complexes with Cu(II). The prepared material was characterized by gas chromatography using unsaturated linear and branched hydrocarbons as well as cyclic and aromatic hydrocarbons. The occurrence of specific metal—olefin interactions resulting from the formation of π-complexes during the chromatographic process was observed.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF02311818

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