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Bis-Kronenether der Talopyranose (1985)

Gruber, Harald ; Schröder, Gerhard

Weinheim : Wiley-Blackwell

Liebigs Annalen 1985 (1985), S. 421-425

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ISSN: 0170-2041

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Bis-Crown Ethers of TalopyranoseThe syntheses of mono- and bis-crown ethers of talopyranose 3a, b and 5a, b are described. A ‚sandwich effect′′ is not observed during complexation of tert-butylammonium rhodanide with 5a, b. The corresponding Ka values are surprisingly low. The ammonium ion seems to associate with the ligands preferentially from the ß face.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jlac.198519850219

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