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Homoaromaticity of decamethyl[5]pericyclyne (1993)

Schaad, L. J. ; Hess, B. A. ; Scott, L. T.

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 6 (1993), S. 316-318

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ISSN: 0894-3230

Keywords: Organic Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: It is shown that a theoretical computation of the Dewar resonance energy of decamethyl [5] pericyclyne should give the same value for the homoaromaticity of this compound as that calculated earlier from heat of hydrogenation measurements. Both methods show this quantity to be small, but the accuracy of the methods appears insufficient for more exact agreement.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/poc.610060510

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