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  • Electronic Resource  (4)
  • Physical Chemistry  (4)
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  • Electronic Resource  (4)
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  • 1
    Electronic Resource
    Electronic Resource
    A shock tube study of the reaction of the hydroxyl radical with H2, CH4, c-C5H10, and i-C4H10 (1989)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 21 (1989), S. 485-498 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reactions of the hydroxyl radical, OH, with several reactants have been studied near 1200 K in shock tube experiments in which UV absorption was used to monitor the OH concentration. The values of the rate coefficients were found to be 2.7 × 1012, 2.6 × 1012, 2.8 × 1013, and 1.26 × 1013 cm3/mol-s for the reactions of OH with hydrogen, methane, cyclopentane, and isobutane, respectively. These measured values are compared with previous experimental results and transition-state theory calculations.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550210702
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    A shock tube study of the reaction of methyl radicals with hydroxyl radicals (1991)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 23 (1991), S. 1017-1033 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The reaction of CH3 with OH has been studied near 1200 K and 1 atmosphere pressure in shock tube experiments in which UV absorption was used to monitor [OH]. A rate coefficient of (1.1 ± 0.3) × 1013 cm3/mol-s was measured for removal of OH by CH3. This measured value is compared with previous experimental data and calculations. Several possible reaction channels are discussed, and although products were not monitored, it seems probable, on the basis of other work and theoretical estimates, that the primary mechanism (≃75%) for the removal of OH by CH3 at these conditions is their combination to form CH3OH. Rate coefficients of (5.3 ± 0.8) × 1012 and (9.0 ± 1.4) × 1012 cm3/mol-s were measured for the reactions of OH with acetone and ethane, respectively, at the same temperature and pressure.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550231106
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    A shock tube study of the reactions of the hydroxyl radical with several combustion species (1991)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 23 (1991), S. 1075-1094 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reactions of the hydroxyl radical, OH, with several organic species of interest in combustion chemistry have been studied near 1200 K and 1 atm in shock tube experiments in which UV absorption was used to monitor the OH concentration. Rate coefficients were measured for the reactions of OH with 2,3-dimethylbutane, isooctane, neooctane, ethylene, propylene, acetylene, formaldehyde, methanol, and ethanol. The values were found to be (in units of 1012 cm3/mol-s): 21, 22, 18, 2.6, 9.6, 0.28, 12, 5.2, and 5.3. These measured values are compared with previous experimental results and, where appropriate, transition-state theory calculations.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550231203
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    Paper (German National Licenses)
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  • 4
    Electronic Resource
    Electronic Resource
    A shock tube study of the reaction of the hydroxyl radical with propane (1984)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 16 (1984), S. 1557-1566 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The rate coefficient for the reaction of the hydroxyl radical, OH, with propane has been measured at 1220 K in shock tube experiments, and a value of (1.58 ± 0.24) × 1013 cm3/mol s was obtained. This measured value is compared with previous experimental results and a transition-state theory calculation.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550161209
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    Paper (German National Licenses)
    Fulltext
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