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  • 1
    Electronic Resource
    Electronic Resource
    Kristallographische Interpretation der Feinstruktur der B-Granula in den Langerhansschen Inseln der Ringelnatter, Natrix n. natrix (L.) (1972)
    Springer
    Cell & tissue research 131 (1972), S. 559-570 
    Details
    ISSN: 1432-0878
    Keywords: Islets of Langerhans ; Grass-snake ; Crystalline B-granules ; Ultrastructure ; Crystallography
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Description / Table of Contents: Zusammenfassung Kristalline B-Granula im Pankreas der Ringelnatter besitzen die Form von Rhombendodekaedern (a ≈ 11 nm, kubisch-raumzentriertes Gitter). Diese Diagnose wird abgeleitet von den Ergebnissen der dreidimensionalen Rekonstruktion von Serienschnitten, der optischen Diffraktometrie und aus dem Vergleich mit Kristallmodellen. Die Bedeutung kristalliner B-Granula wird erörtert.
    Notes: Summary Crystalline B-granules of grass-snake islets of Langerhans have been shown to possess the shape of rhombic dodecahedra (a ≈ 11 nm, cubic body-centered lattice). Three-dimensional reconstructions from serial sections, optical diffractometry and comparison with crystal models were the techniques utilized. The significance of crystalline B-granules is discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00306971
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  • 2
    Electronic Resource
    Electronic Resource
    Microangioarchitecture of the islets of Langerhans in the snakes,Naja naja, Vipera russelli, andEchis carinatus (1991)
    Springer
    Cell & tissue research 266 (1991), S. 83-88 
    Details
    ISSN: 1432-0878
    Keywords: Islets of Langerhans ; Microangioarchitecture ; Corrosion casts ; Scanning electron microscopy ; Naja naja, Vipera russelli, Echis carinatus (Serpentes)
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary Due to a decided lack in the literature of reports on the microangioarchitecture of the pancreas of snakes, an analysis was performed in three different species of two different ophidian families with the use of cast preparations and complementary scanning electron microscopy. The vascular architecture reflects the lobular substructure of the pancreas; the organ is supplied by branches of the superior mesentric artery. Coiled lobular arteries and arterioles continue into a meshwork of capillaries. Dilated capillaries of the endocrine portion of the pancreas are an integral component of this fine capillary network. A few very small capillaries establish a connection between the endocrine and the exocrine pancreas. The other capillaries drain into venules, which ultimately join their respective veins. No interspecific differences were noted in the vascularization of the pancreas of the three ophidian species examined. The present results suggest the existence of arterio-venous anastomoses and speak against the presence of a portal system, but establish a feed-forward capillary connection from the endocrine to the exocrine component of the ophidian pancreas.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00678714
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Kinetic and mechanistic studies on the complexation and anation of dioxotetracyanomolybdate (IV) with 2,2′-bipyridyl in aqueous solution (1996)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 28 (1996), S. 705-711 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dioxotetracyanomolybdate(IV) has been found to form a 1 : 2 complex with 2,2′-bipyridyl. The kinetics of the reaction has been studied over the pH range 5.3-8.7 by visible spectrophotometry under pseudo conditions. The effect of the 2,2′-bipyridyl and dioxotetracyanomolybdate(IV), temperature, ionic strength, and pH on the reaction rate was determined. The reaction follows first-order kinetics with respect to dioxotetracyanomolybdate(IV) ion and fractional-order kinetics with respect to 2,2′-bipyridyl. Values for the outer-sphere complex formation constant (Kos2) and rate constants (k2) were also calculated from the kinetic data. It was found that rate of the reaction increases with the decreasing pH. The following rate equation based on the outersphere complexation equilibrium preceding the associative interchange has been derived.\documentclass{article}\pagestyle{empty}\begin{document}$$\rm {{1}\over{{\it k}_{obs}}}={{1+K_{a2}[H^+]}\over{B_1[2,2\prime-bipyridyl]}}+B_2$$ ${\rm where}$ $\rm B_1={\it k}_1K_{os1}+{\it k}_2K_{os2}[H^+]K_{a2}$ ${\rm and}$ $\rm B_2={{K_{os1}+K_{a2}K_{os2}[H^+]}\over {{\it k}_1K_{os1}+{\it k}_2K_{os2}[H^+]K_{a2}}}.$\end{document}On the basis of the observed results probable mechanism has been proposed. © 1996 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.9
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  • 4
    Electronic Resource
    Electronic Resource
    Photoreactivity of diethanolamine with octacyanomolybdate(IV) and -tungstate(IV) (1997)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 29 (1997), S. 819-824 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An investigation is presented on the kinetics of complexation of aqueous solution of octacyanomolybdate (IV) and -tungstate (IV) after photoinitiation with one of the mixed group ligands containing both N and O, diethanolamine (DEOA), [NH(CH2CH2OH)2]. Under the steady state conditions and with approximation k3 〉 k4 over a range of concentrations, the observed rate law is:\documentclass{article}\pagestyle{empty}\begin{document}$$ \cal{k}_{\rm obs.}={\cal{k}_{2}\cal{k}_{4}\rm {I}_{a}[\rm {OH}^{-}][\rm {NH}(\rm{CH}_{2}\rm{CH}_{2}\rm{OH})_{2}]\over \rm{I}+\it \cal{k}_{2}[\rm {OH}^{-}]} $$\end{document}The complexes show shift in electronic transition supporting the mechanism of association of the ligand followed by the abstraction of some small molecules and then substitution by the ligand. The presence of the specific isobestic point also contributes towards the stability of the complex. The rate constant and quantum yield values are dependent on both the concentration of the metal cyanide and the ligand predicting the mechanism to be an associative one. The complexes have strong absorption in the visible range and are assigned metal-to-ligand electron transfer transition. © 1997 John Wiley & Sons, Inc. Int J Chem Kinet 29: 819-824, 1997
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
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