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Chemistry in mixtures of Kr with Ar and He illuminated with Kr resonance radiation (1982)

Young, Robert A.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 14 (1982), S. 93-130

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The formation and destruction of excited rare-gas dimers have been studied using resonance optical excitation of high-pressure gas mixtures containing Kr. From an analysis of the resulting emission, 19 reaction rate coefficients have been inferred. It is concluded that atom-atom interchange processes play a major role in rare-gas eximer formation, and that stepwise relaxation down the eximer vibrational ladder is less important than multistep relaxation due to atom-atom exchange in the excited eximer.

Additional Material: 16 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550140202

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