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  • 1970-1974  (2)
  • 1950-1954
  • Physics  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 10 (1972), S. 2655-2660 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The nature and behavior of free radicals induced in acetylated cotton celluloses irradiated with γ-rays have been studied by electron spin resonance (ESR) spectroscopy. Dehydrogenation and deacetylation appear to be responsible for the free radicals observed from samples irradiated at 77°K. The degree of substitution enhanced the yield of acetyl radicals when the samples were irradiated at 77°K and adversely affected the overall radical concentration when irradiation was done at 300°K. In addition, the ESR spectra of samples irradiated under vacuum at 300°K were more intense than those obtained from samples irradiated in air. The nature, yield, and post-irradiation behavior of the primary radicals are discussed in the light of the ultimate chemical effects observed.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: With a view to assessing the role of chemical substitutions in the modification of radiation effects on cotton fibers, the induction and post-irradiation behavior of free radicals in γ-irradiated pure, mercerized, benzoylated, and allylated cottons have been investigated by ESR spectroscopy. While mercerization and allylation were found to influence both the nature and yield of radicals, benzoylation reduced only the yield. These substitutions, which have been found to protect cotton fibers against radiation damage, therefore act differently at the molecular level.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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