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Structure and Morphology of a Polyether/Polyacrylate Semi-interpenetrating Polymer Network (2000)

Schilling, F. C. ; Katz, H. E. ; Bair, H. E.

Springer

Journal of thermal analysis and calorimetry 59 (2000), S. 83-92

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ISSN: 1572-8943

Keywords: cationic and photoinitiated polymerization ; DSC ; interfacial mixing ; interpenetrating polymer network (IPN) ; glass transition temperature ; NMR ; quantitative thermal analysis of phases ; reactive epoxy and acrylate systems ; Tg broadening

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract In this study NMR and DSC are used to probe the structure, thermal characteristics and morphology of a network formed from a diepoxide/acrylate system. Separate chemistries are employed to polymerize the diepoxide and acrylate components. The cationic polymerization of the diepoxide exhibits excellent selectivity in producing a crosslinked polyether network without affecting the acrylate monomer. Subsequent photoinitiated free-radical polymerization of the acrylate produces a phase separated, semi-interpenetrating polymer network (SIPN).

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1023/A:1010123610324

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Model copolymers of ethylene with butene-1 made by hydrogenation of polybutadiene: Chemical composition and selected physical properties (1985)

Krigas, T. M. ; Carella, J. M. ; Struglinski, M. J. ; [et al.]

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Physics Edition 23 (1985), S. 509-520

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ISSN: 0098-1273

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Hydrogenation of polybutadienes with from 8 to nearly 100% vinyl content was used to prepare a series of model copolymers of ethylene and butene-1 with uniform microstructures and narrow molecular weight distributions. They range from readily crystallizable to completely amorphous, depending on the frequency of ethyl side branches (2-50 per 100 skeletal carbons). Melting temperature, secondary transition temperature, density, plateau modulus for the melt, and elastic modulus for the solid were obtained as functions of branch content. The effect of crystallinity on the secondary transition and modulus of the solid is discussed.

Additional Material: 3 Ill.