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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 16 (1978), S. 169-177 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A series of methyl methacrylate (MMA)-methacrylic acid (MAA) copolymers containing up to 50% methacrylic acid and the respective homopolymers were reproducibly pyrolyzed at 900°C and the fragments identified by gas chromatography (GC) or GC-mass spectroscopy. It was shown that PMMA and the MMA portions of blocky or random copolymers yielded 99% MMA, while a large portion (50-60%) of the MAA broke down to give a wide variety of hydrocarbons via decarboxylation and/or anhydride formation. Both unsaturated aliphatic and aromatic hydrocarbons, as well as the minor products of the MMA decomposition, support free-radical processes for these decompositions. It was also shown that the copolymers readily complex oxygenated solvents (which did not affect decomposition) and metal ions (which markedly affected the products).
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 14 (1976), S. 701-711 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The G values of poly(methyl methacrylates) (PMMA), polycarbonates, and a polylactone for γ-radiation were determined by using a computer-assisted GPC as the primary tool for the measurement of the number-average molecular weights M̄n. The accuracy and precision of the automated GPC were found to have a normalized standard deviation (σ/M̄n) of less than 7%. The G value of PMMA was determined to be essentially independent of molecular weight. For low molecular weight polymers, some nonlinearity in the I/M̄n versus dosage plot was observed at low dosage, i.e., about 1 Mrad.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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