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Optical activity of alternating copolymers of chiral α-olefins with alkyl acrylates (1983)

Aglietto, Mauro ; Carlini, Carlo ; Veracini, Carlo Alberto

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 21 (1983), S. 1203-1215

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Details

ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The synthesis of high-molecular-weight substantially alternating copolymers of alkyl acrylates with optically active α-olefins is reported. “Induced optical activity” on the side-chain ester chromophores, depending on the chemical structure of the chiral α-olefin, is indicated by CD measurements. Data are reported supporting the conclusion that this induced optical activity is related to a preferential chiral conformation of the macromolecules due to a cooperative effect.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1983.170210427

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