ISSN:
0538-8068
Keywords:
Chemistry
;
Physics Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
O(1D), produced from the photolysis of N2O at 2139 Å, reacts with N2O in accord with: \documentclass{article}\pagestyle{empty}\begin{document} $$ \begin{array}{*{20}c} {(2)} & {{\rm O}(^1 D) + N_2 {\rm O} \to {\rm N}_2 + {\rm O}_2 } \\ \end{array} $$ \end{document}\documentclass{article}\pagestyle{empty}\begin{document} $$ \begin{array}{*{20}c} {(3)} & { \to 2{\rm NO}} \\ \end{array} $$ \end{document}We have used the method of chemical difference to obtain an accurate measure of k2/k3 = 0.59 ± 0.01. Furthermore, the quantum yield of production of O(3P), either on direct photolysis or on deactivation of O(1D) by N2O, is less than 0.02 and probably zero.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550020304
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