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Crystallization behaviour of polyoxetanes: poly(oxetane), poly (3,3-dimethyloxetane) and poly(3,3-diethyloxetane) (1983)

Pérez, E. ; Gómez, M. A. ; Bello, A. ; [weitere]

Springer

Colloid & polymer science 261 (1983), S. 571-576

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ISSN: 1435-1536

Schlagwort(e): Poly(oxetane) ; poly(3,3-dimethyloxetane) ; poly(3,3-diethyloxetane) ; crystallization behaviour ; DSC curves ; X-ray diagrams

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie , Maschinenbau

Notizen: Abstract The influence of the crystallization temperature on the melting behaviour and crystalline structure of polyoxetane (PTO), poly(3,3-dimethyloxetane) (PDMO) and poly(3,3-diethyloxetane) (PDEO) has been studied using differential scanning calorimetry (DSC) and X-ray techniques. When PTO is crystallized by cooling from the relaxed melt state, only the orthorhombic modification is obtained. However, PDMO and PDEO can be crystallized in two different modifications depending on crystallization temperature. The effect of the substituents in the stability of main chain conformations in crystalline state is discussed.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF01526622

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