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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 274 (1996), S. 763-771 
    ISSN: 1435-1536
    Keywords: Engulfment ; interfacial energy ; heterocoagulation ; Poly-[styrene] ; Poly-[butylmethacrylate]
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract It can be predicted that, provided the interfacial energies are well chosen for two individual particles, then it is possible to engulf one particle into the other. This has now been achieved experimentally using poly-[butylmethacrylate] particles as the host material and poly-[styrene] particles for engulfment. Initially, anionic poly-[styrene] particles were heterocoagulated onto electrosterically stabilised cationic particles of poly-[butylmethacrylate]. Then on heating the heterocoagulated units above the glass transition temperature of the latter engulfment occurred.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 275 (1997), S. 274-283 
    ISSN: 1435-1536
    Keywords: Key words Heterocoagulation ; polymer colloids ; poly-[styrene] ; poly-[butylmethacrylate] ; encapsulation ; core-shell particles
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract  By means of heterocoagulation anionic poly-[styrene] particles were coated with smaller electrosterically stabilised cationic particles of poly-[butyl methacrylate]. On heating the heterocoagulated units 45 °C above the glass transition temperature of poly-[butyl methacrylate], as predicted theoretically, the latter polymer spread over the surface of the poly-[styrene] particle to give a composite particle with a core-shell structure. It was found that the extent of packing of the small particles on the larger core particle was a critical feature of the coating process.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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