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  • Articles: DFG German National Licenses  (58)
  • Polymer and Materials Science  (58)
  • 1
    Electronic Resource
    Electronic Resource
    Selective separation of water-ethanol mixture through synthetic polymer membranes having carboxylic acid as a functional group (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1585-1597 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Separation of water-ethanol mixture through a membrane was carried out by pervaporation using a membrane which provided a hydrogen-bonding interaction. A membrane obtained from poly(acrylic acid-co-acrylonitrile) was effective for a selective separation of water from aqueous ethanol solution by pervaporation technique. Spectroscopic and flux analyses verified that this high selectivity toward water was attributed to the hydrogen-bonding interaction between water and acrylic acid (carboxylic acid) unit in the membrane. On the other hand, a membrane from poly(acrylic acid-co-styrene) preferentially permeated ethanol in the low water feed concentration region.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240716
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  • 2
    Electronic Resource
    Electronic Resource
    Synthesis of polyurea by direct polycondensation of 4-aminophenyl ether with lithium carbonate (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1915-1921 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polyureas of high molecular weight were obtained by the direct polycondensation of 4-aminophenyl ether with lithium carbonate in the presence of triphenylphosphine (Ph3P), hexachloroethane (C2Cl6), and pyridine. Reaction conditions, such as the molar ratios of Ph3P and C2Cl6 to the monomers, monomer concentrations, reaction temperatures, reaction times, and kind of solvents, had a significant effect on the yield and the molecular weight of the resulting polyureas. The polyurea having the highest solution viscosity of 0.91 dL/g was obtained with the molar ratio of Ph3P/C2Cl6/monomers = 2.4/2/1 in the mixed solvent of N-methyl-2-pyrrolidone and pyridine at 80°C.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1986.080240813
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  • 3
    Electronic Resource
    Electronic Resource
    Separation of water from aqueous ethanol solution through quaternized poly(4-vinylpyridine-co-acrylonitrile) membranes (1988)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 26 (1988), S. 335-340 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1988.080260133
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  • 4
    Electronic Resource
    Electronic Resource
    Preparation and polarizing microscopic study of poly(alkyl acrylate-g-polybenzamide)s (1987)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 25 (1987), S. 727-730 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1987.080250224
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  • 5
    Electronic Resource
    Electronic Resource
    Synthesis of ultra-thin films of aromatic polymers at air/water interface (1990)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 3221-3230 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ultra-thin films of and precursor polymers for polybenzimidazole (PBI), polybenzoxazole (PBO), or polybenzothiazole (PBT) were formed at air/water interface by spreading monomers and then polymerizing on the water surface. These thin films could be deposited onto appropriate substrates by using the LB method of horizontal lifting. Moreover, the heat-treatment of the built-up films of the precursor polymers of PBI, PBO, and PBT formed the ultra-thin films of high temperature polymers. The resulting ultra-thin films had uniform and controllable thickness, but remained fairly stable when subjected to temperature up to 300°C. They also had good solvent resistance.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1990.080281202
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  • 6
    Electronic Resource
    Electronic Resource
    In-situ direct polycondensation in polymer matrices. II. In-situ direct polycondensation in styrene-butadiene block copolymers (1993)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 31 (1993), S. 597-602 
    Details
    ISSN: 0887-624X
    Keywords: in-situ ; direct polycondensation ; styrene-butadiene block copolymers aromatic polyester ; composites ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Direct polycondensation of 3-substituted-4-hydroxybenzoic acid was carried out in solutions of styrene-butadiene block copolymers (SBS) at room temperature in the presence of triphenylphosphine and hexachloroethane as an initiator for the direct polycondensation of these monomers. Solution casting after the direct polycondensation provided opaque films in which the aromatic polyester was finely dispersed within the matrix of SBS. Mechanical properties of these films were examined by tensile tests. A great improvement of tensile strength was achieved by the incorporation of phenyl substituent in the resulting polyester. In-situ direct polycondensation leads to the formation of new composites of rigid polymers and flexible polymers. © 1993 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1993.080310301
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  • 7
    Electronic Resource
    Electronic Resource
    Ionic conductivity and side chain relaxation in polyglutamates having oligo(ethylene oxide) chains (1993)
    New York, NY : Wiley-Blackwell
    Polymers for Advanced Technologies 4 (1993), S. 179-187 
    Details
    ISSN: 1042-7147
    Keywords: Polymer electrolytes ; Poly(ethylene oxide) ; Polyglutamates ; α-Helix structure ; Ionic conductivity ; Dielectric relaxation ; Side chain relaxation ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: New polymer hosts to form polymer electrolytes, poly[methoxy-oligo(ethylene oxide)-L-glutamate] (PMnEOG, n = 1, 2, 3 and 7, n stands for the number of ethylene oxide units), have been prepared in order to study the correlation between the side chain relaxation and the ionic conductivity of PMnEOG/LiClO4 complexes. The main chains of PMnEOGs form a rigid rod-like structure (α-helix structure) in the solid state both in the absence and the presence of LiClO4. The oligo(ethylene oxide) side chains begin to be mobile at temperatures lower than 0°C, while the rigid main chains do not move up to 100°C. The side chains show a preferential solvation of incorporated LiClO4. The ionic conductivity of 10-7-10-6S/cm is attained in PM3EOG/LiClO4 and PM7EOG/LiClO4 complexes at room temperature, where only the short side chain motion contributes to the ionic transport. The temperature dependencies of the side chain relaxation time and ionic conductivity increase with increasing the side chain length when the temperature dependencies are normalized by the temperatures based on the glass transition temperatures of the side chains, which indicates strong cooperation between the side chain motion and the ion transport. The possibility of fast ion transport by short side chain relaxation is discussed.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pat.1993.220040218
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  • 8
    Electronic Resource
    Electronic Resource
    Active transport membrane for chlorine ion (1980)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 25 (1980), S. 1419-1425 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A specific functional group that could interact with ions was introduced in a synthetic membrane to achieve an active transport of ions. One way to synthesize the active transport membrane was to introduce a functional group which has a tautomerism upon pH changes in an aqueous solution. A polymer having pendent N-hydroxyethyl amide groups was synthesized to form a membrane, and the membrane was fixed in a cell as a partition film, in which one side of the solution was adjusted to be acidic and the other side basic. It was then possible to transport chlorine ion through the membrane owing to the carrier functions caused by tautomerism of the N-hydroxyethyl amide group from the acidic to the basic sides. The transport of the chlorine ion was not dependent on diffusion control.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1980.070250715
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  • 9
    Electronic Resource
    Electronic Resource
    Synthesis and properties of photosensitive rubbers. IV. Photosensitive rubbers from hydroxyethyl cinnamate and polyisoprene modified with maleic anhydride (1983)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 28 (1983), S. 543-557 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polyisoprene in o-dichlorobenzene solution were reacted with maleic anhydride at 180°C under nitrogen atmosphere to form modified polyisoprene with α-substituted succinic anhydride groups. These groups were converted by reaction with hydroxyethyl cinnamate in pyridine at 25°C to cinnamate groups. Various amounts of cinnamate groups as photosensitive groups could be easily introduced into polyisoprene up to 75 mol % toward polyisoprene repeating units. Polymer glass transition temperatures of the products rose linearly from -70°C for polyisoprene to 60°C with increasing amounts of the side groups. The solution viscosity of the products in chloroform decreased from 9.34 for polyisoprene to 0.77 with increasing amounts of the side groups. The photosensitivity of the polyisoprene, which is based on the photodimerization of the cinnamate groups, was higher than that of polypentenamer having cinnamate groups due to the interaction by the free carboxylic acids neighboring with the cinnamate groups. The photosensitivity of the cinnamate group was kinetically evaluated in terms of the dependence on the polymer glass transition temperature. The interaction by the free carboxylic acid groups in the polyisoprene reduced the dependence of the photosensitivity on the mobility of the polymer segments. Linear relationship between observed rate constants of the photodimerization and (TUV - Tg + 50)-1 was obtained and the slope of the line changed and became very small at higher glass transition temperatures.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1983.070280210
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  • 10
    Electronic Resource
    Electronic Resource
    Relationship between electron sensitivity and chemical structures of polymers as EB resists. II. Acetalized polyvinyl alcohol as new negative EB resists (1983)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 28 (1983), S. 2433-2437 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1983.070280726
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