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  • 1
    Electronic Resource
    Electronic Resource
    The stability of poly(ether urethane)/polydimethylsiloxane interpenetrating polymer networks (1995)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 55 (1995), S. 733-740 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Interpenetrating polymer networks (IPNs) are a special type of polymer blend consisting of two polymer networks synthesized and/or cross-linked independently within each other. One potential approach for the preparation of composite materials from polymers having desirable physical characteristics obtained by modifying their surfaces with physiologically acceptable polymers involves IPN technology. An IPN based on a poly(ether urethane) and polydimethylsiloxane has been synthesized and charaterized using optical microscopy, dynamic mechanical analysis, and scanning electron microscopy. The stability of poly(ether urethane)/polydimethylsiloxane composites were studied in hydroxyl radical aqueous solutions over 30 weeks. The data suggest that these composites have good potential for biomedical applications. © 1995 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1995.070550509
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Effects of radiation on mechanical properties of polybutadiene/polystyrene blends (1995)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 58 (1995), S. 85-94 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Blends containing 3 wt % low molecular weight polybutadiene (PB) in a polystyrene (PS) matrix were prepared via a precipitation technique that yielded spherical, submicron pools of PB. Tensile specimens made from these blends were then irradiated with high energy electrons in air at dose levels from 0 to 70 Mrads. The blends, which previously showed high levels of toughness approaching that of high impact PS, lost all enhanced toughness when irradiated above 10 Mrads. Analysis of pure PS specimens irradiated over the dose range from 0 to 45 Mrads showed no appreciable dependence of mechanical behavior on dose level. Molecular weight studies of the polybutadiene demonstrated only a very modest increase in molecular weight in the dose range studied here; therefore, reduced mobility of the PB in the blends was not the reason for the dramatic drop in toughness with radiation dose. It was concluded that radiation-induced scission of the PS near the surface of the blends resulted in a significant local reduction in molecular weight. This degraded layer led to premature craze failure and hence a low level of toughness. It was demonstrated that the absence of oxygen during the irradiation process or the removal of the scissioned surface layer via mechanical abrasion resulted in a recovery of toughness. © 1995 John Wiley & Sons, Inc.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1995.070580109
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    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    Cyclopolymerization studies of diallyl-and tetraallylpiperazinium salts (1996)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 61 (1996), S. 1077-1085 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The quaternary ammonium salt 1,1-diallyl-4-formylpiperazinium chloride (7) was synthesized in good yields. The monomer (7) on cyclopolymerization in the presence of ammonium persulfate in water solution at 90°C afforded water-soluble polymer (8) having excellent rheological properties. The synthesis of the polymer (8) paves the way for the preparation of a novel class of polymers: dicationic polyelectrolytes (9) and cationic polymer (10) with a basic nitrogen as well as a quaternary nitrogen. Effects of monomer, initiator, and additives concentration were studied. Cyclopolymerization of (7) with 1,1,4,4-tetraallylpiperazinium dichloride (12) gave ion-exchange resins with excellent swelling coefficients. © 1996 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
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