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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 13 (1975), S. 129-136 
    ISSN: 1572-9613
    Keywords: Fluctuation relation ; surface tension ; equation of state ; quantum corrections ; hard sphere fluid ; scaled particle theory
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The leading term of the high-temperature quantum corrections to the scaled particle theory of the hard sphere fluid have been obtained. This provides approximate corrections to the pressure, surface tension, and reversible work to create a spherical cavityW(r) of the quantum mechanical hard sphere fluid. A number of exact identities valid for the classical hard sphere fluid are shown to apply also to the quantum mechanical hard sphere fluid, including the fluctuation relation betweenW(r) and the probability of finding a cavity of radius at leastr.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 30 (1992), S. 835-843 
    ISSN: 0887-624X
    Keywords: interpenetrating polymer networks ; poly(urethane carbonate) ; polyvinyl pyridine ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Simultaneous interpenetrating polymer networks (IPN's), pseudo IPN's, and liner blends of aliphatic poly(carbonate-urethane) (PCU) and polyvinyl pyridine (PVP) have been prepared and characterized by DSC, DMA, and TEM. The full IPN's of PCU and PVP had a single phase morphology only above 50 wt % PCU, as determined by both DSC and DMA and confirmed by transmission electron microscopy (TEM). However, in both pseudo IPN's of PCU and PVP and in their linear blends there exist multiple glass transitions and melting points seen by DSC and DMA indicating phase incompatibility. The full IPN's exhibited superior ultimate mechanical properties and solvent resistance as compared to the pseudo IPN's, liner blends, and the pure crosslinked PCU and PVP networks.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 34 (1996), S. 1823-1826 
    ISSN: 0887-624X
    Keywords: hybrid inorganic/organic IPN ; porous materials ; poly(styrene) ; silica gel nanotubes ; mesoporous hexagonal silica ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 34 (1996), S. 1049-1058 
    ISSN: 0887-624X
    Keywords: interpenetrating polymer networks (IPNs) ; differential scanning calorimetry (DSC) ; scanning electron microscopy (SEM) ; nonlinear optical (NLO) properties ; second harmonic generation (SHG) ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: We report the synthesis and characterization of interpenetrating polymer networks (IPNs) exhibiting nonlinear optical (NLO) properties. The network consists of aliphatic polycarbonate urethane (PCU) and poly(methyl methacrylate-co-N,N-disubstituted urea), with a nonlinear optical (NLO) chromophore incorporated into N,N-disubstituted urea. The full IPNs have only one Tg, as determined by differential scanning calorimetry (DSC), together with scanning electron microscopy (SEM) observations, suggest a single phase morphology. The thin films of IPNs are transparent and the unpoled samples produced second harmonic generation (SHG) signals at room temperature. This result indicates that the NLO chromophore is oriented noncentrosymmetrically during the IPN formation process and is tightly held between the permanent entanglements of the two component networks of the IPN. © 1996 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 36 (1998), S. 553-561 
    ISSN: 0887-624X
    Keywords: interpenetrating networks ; nonlinear optics ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Two-component simultaneous interpenetrating networks (IPN) of thepoly(4′-[[2-(methylacryloxy)ethyl]ethylamino]-4-nitroazobenzene-co-methyl meth-acrylate) (PDR1MA-co-MMA)/poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) system, the PDR1MA/PPO system and 4′-[[2-(acetoxy)ethyl]ethylamino]-4-nitroazo benzene (ACDR1) doped MMA/PPO system were synthesized and characterized. As studied by differential scanning calorimetry (DSC) the full IPNs of the PDR1MA-co-MMA/PPO system and the PDR1MA/PPO system showed a single Tg varying with the PPO composition. A single-phase morphology of the full IPNs was also indicated by scanning electron microscopy (SEM). Transparent films were cast onto clean microscopic glass slides and poled at 190°C for 1 h. The UV-VIS absorption spectra of the three IPN systems before and after curing and corona poling showed a shift in the maximum absorption due to the induced alignment of the nonlinear optical chromophores in the IPN systems. The absorption intensity of the full IPNs remained same after heating at 120°C for 72 h, indicating that the electric field-induced alignment is stable in the full IPN materials. Preliminary second harmonic generation (SHG) data on these IPNs are presented. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 553-561, 1998
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 26 (1988), S. 2589-2596 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis and characterization of pseudo or semi- and full-interpenetrating polymer networks (IPNs) of poly(2,6-dimethyl-1,4-phenylene oxide) and polydimethylsiloxane were performed. We observed that in full IPNs, the elasticity of the IPN samples increased very drastically, as the composition of polydimethylsiloxane increased (i.e. 0-60%) while the tensile strength (TS) and the glass transition temperature (Tg) decreases. The pseudo IPNs appeared to consist of two phases while the full IPNs of lower siloxane content were miscible.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 27 (1989), S. 3363-3370 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Simultaneous full and pseudo- interpenetrating polymer networks of poly(2,6-dimethyl-1,4 phenylene oxide) (PPO) and a poly(urethane acrylate) (PUA) have been synthesized and characterized by differential scanning calorimetry, ultimate mechanical properties, and electron microscopy. No evidence of phase separation was detected in both the full and pseudo- PPO/PUA networks. The networks exhibited a single glass transition temperature at all the compositions studied. A maximum in tensile strength to break was observed at 25 PPO/75 PUA composition by weight percent.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 29 (1991), S. 1031-1038 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: We report the synthesis and characterization of interpentrating polymer networks (IPN's), pseudo INPN's, and blends of urethane-containing aliphatic polycarbonates (PCU) and polymethyl methacrylate (PMMA). The simultaneous full IPN's of PCU's and PMMA over the whole composition range have only one Tg, as determined by DSC and DMA which, together with transmission electron microscopy observations, suggest a single phase morphology even though the linear chain blends are completely immiscible. The full IPN's exhibit a maximum tensile strength at a certain composition, and superior solvent and heat resistance as compared to the pseudo IPN's, linear blends, and the pure crosslinked PCU's and PMMA.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 29 (1991), S. 1219-1221 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 30 (1992), S. 2749-2753 
    ISSN: 0887-624X
    Keywords: interpenetrating polymer networks ; polycarbonate-urethane ; polybutadiene ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Interpenetrating polymer networks (IPN's), pseudo IPN's and linear blends of urethane-containing aliphatic polycarbonate (PCU) and polybutadiene (PB) have been prepared and characterized. The simultaneous full IPN's of PCU and PB over the whole composition range (15-85% by weight PCU) exhibit a single phase morphology even though the linear chain blends are completely immiscible, as determined by DSC and confirmed by transmission electron microscopy (TEM). However, in both pseudo IPN's of PCU and PB there appeared multiple (melting and glass) transitions in DSC measurements and phase separation was observed by TEM. © 1992 John Wiley & Sons, Inc.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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