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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 22 (1978), S. 27-42 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Glassification, cast polymerization, and physical properties of monomeric system including diethylene-glycolbisallyl carbonate (CR-39) was investigated. Addition of other monomers CR-39 was investigated CR39- polyfunctional monomer and CR-39-methyl methacrylate-polyfunctional monomer systems were found to form stable glassy state applicable to radiation-induced casting and good in physical property. Two-step polymerization method consisting of pre-irradiation and post-catalytic polymerization necessary to complete casting. It was found that these newly found CR-39 modified systems could be casted efficiently in much shorter time cycle than catalytic process without forming optical strain. Physical properties of casted polymer such as impact resistance and heat durability were sufficient for practical use.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The applicability to radiation-induced cast polymerization of polyfunctional monomers or systems including them was studied. Most of polyfunctional monomers could be glassified and were applicable to radiation casting. The effect of tetraethylene glycol diacrylate on inner-plasticized comonomer systems was studied in detail. It was found that the glass-forming property increased by the addition of tetraethylene glycol diacrylate and that heat durability improved satisfactorily. The formation of optical strain in casting was relatively easier in polyfunctional monomers including systems due to inner stress, although the merit of radiation casting was still obvious.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Previously, it was found that organic glass material having no optical strain could be cast efficiently in a very short time by radiation-induced cast polymerization of glass-forming monomers. In this report, practical useful monomer systems having glass-forming property and good physical properties were investigated. Several inner plasticized comonomer systems of excellent impact resistance were found which could be glassified and applied to radiation casting. These systems included butyl acrylate or hexanediol monoacrylate as inner plasticized component. Physical properties other than impact resistance were tested. The casting polymerization was studied, and it was found that polymers without optical strain could be obtained in a remarkably short time.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 22 (1978), S. 823-832 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: It was previously reported that excellent mar resistance coating systems could be obtained by the combination of silicone compounds and vinyl compounds, such as KBM 403-GMA systems. Radiation-induced polymerization was the most efficient means of prepolymerization of give the viscosity suitable for coating. In this report, change in conversion and the predominant mechanims of prepolymerization were investigated by measuring the change in refractive index. It was shown that the conversion change and the predominant prepolymerization mechanism could be identified by the refractive index. The relationship between the refractive index and coating properties such as film thickness and haze value was also studied. Dripping of GMA prepolymer occurred, and coating thickness was small in GMA including prepolymer systems obtained predominantly by radical mechanism; the thickness was relatively large in the prepolymer systems obtained by epoxy ring opening-type polymerization mechanism. However, the mar resistance in the former was excellent in spite of reduced thickness.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Casting of methyl methacrylate prepolymer by irradiation at relatively low temperatures was studied. It was difficult to completely glassify the methyl methacrylate monomer and prepolymer, and so the casting was carried out at temperatures above its melting point (-48°C). The optical strain formed in this stream remained of the stress type, and optical strain formation was reduced with increasing prepolymer concentration and decreasing temperature.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 22 (1978), S. 487-496 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A mar-resistant coating system was obtained by screening combinations of silicone and vinyl compounds. It was found that binary systems, such as the γ-glycidoxypropyltrimethoxysilane-glycidyl methacrylate system, were excellent not only in mar resistance but also in adhesion to base resin polymers. Haze values of these coatings, after the sand-falling test, reached less than 10%. The coating process consisted of three steps: the preparation of prepolymer, the coating to plastic surface, and the curing of the coating by heating. It was found that the prepolymerization step could be performed by irradiation very conveniently; the control of viscosity for coating application and thickness control could be possible without any gel formation. These coatings were also good in weather resistance due perhaps to the good adhesion to base resin and could be applicable to plastic spectacles, glazing materials, and a variety of other products.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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