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  • 1
    Electronic Resource
    Electronic Resource
    Conducting carbon-nitrogen pyropolymers derived from cyanogen (1985)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 23 (1985), S. 517-523 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Electropolymerization of cyanogen in acetonitrile containing an electrolyte yields a poly(cyanogen). Its structure involves an open-structured dimer derived from the heterocyclic anion C7N7- mixed with a sequence of nitrile-substituted, conjugated carbon-nitrogen bonds. Although this polymer is an insulating solid, pyrolysis in vacuo to 700°C leads to highly conducting carbon-nitrogen pyropolymers via crosslinking and nitrogen elimination. The 700° pyropolymer has a carbon-nitrogen ratio of 5:1, a room temperature conductivity of 1 Ω-1 cm-1, and an activation energy for conduction of ∼0.03 eV.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1985.170230225
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  • 2
    Electronic Resource
    Electronic Resource
    134. Beschreibung von Eigenschaften fluider Mischungen mit kubischen Zustandsgleichungen - Kritische Analyse klassischer und moderner Mischungsregeln (1994)
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 66 (1994), S. 1239-1239 
    Details
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cite.3306609135
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  • 3
    Electronic Resource
    Electronic Resource
    Application of Matrix Algebra to Stoichiometry of a Chemical Reaction System and Dimensional Analysis (1988)
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 60 (1988), S. 483-486 
    Details
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cite.330600612
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  • 4
    Electronic Resource
    Electronic Resource
    Hydrophilic interpolymer membranes from crosslinked blends of poly(vinylalcohol), poly(styrene sodium sulfonate) and poly(vinyl methyl ether-alt-maleic anhydride) (1979)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 2611-2625 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Interpolymer ion exchange membranes were prepared from a compatible casting solution that contained poly(styrene sodium sulfonate), poly(vinyl methyl ether-alt-maleic anhydride), and poly(vinyl alcohol). Crosslinking of the films was accomplished through the formation of ester linkages that were stable in aqueous environments. Membrane properties (water content, capacity, concentration potential, equivalent conductivity) were measured over a wide range of membrane compositions. Ultrafiltration was carried out with a feed solution that was 0.01N in KCI and 15 ppm in erythrosin. Rejection and hydraulic permeability data were reported as a function of membrane composition.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1979.070230907
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  • 5
    Electronic Resource
    Electronic Resource
    Solute-membrane interactions in hyperfiltration (1987)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 33 (1987), S. 1809-1822 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The performances of several composite membranes (PEC-1000, Teijin, HR-95, HR-98) and one asymmetric membrane (Solrox SC-200) in hyperfiltration are compared at 25°C using different aqueous feed solutions (0.1M and 0.5M NaCl, 0.5M 1,3-and 1,4-dioxan, 0.1M benzyl alcohol and 2-methoxybenzyl alcohol, 1,2- and 1,4-butandiol, and Triton feed solution). The effects of solute dissociation, polarization, and hydrogen bonding ability on solute permeability are discussed; steric effects are also being considered. Strong solute-membrane interactions are exhibited in hyperfiltration by systems with distinct hydrogen bonding capabilities of the solute with functional sites of the membrane matrix. Knowledge of solute-membrane interactions can be useful for elaborating separation and transport mechanisms.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1987.070330532
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  • 6
    Electronic Resource
    Electronic Resource
    Depolymerization of poly(ethylene terephthalate) resin under pressure (1991)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 42 (1991), S. 1501-1507 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The process of depolymerization of PET resin by EG glycolysis under pressure is investigated. The kinetics of this pressurized depolymerization of PET resin is discussed. It was found that the rate of depolymerization is dependent of temperature, pressure, and concentration ratio of EG to PET. The rate of depolymerization is proportional to the square of EG concentration and faster than that under atmospheric pressure. Glycolyzed products under pressure consist of the PET monomer, BHET, and oligomers, mostly dimer and trimer. An equilibrium between BHET and oligomers is attained quickly soon after the depolymerization step is completed in the case of a higher ratio of EG/PET used. In the case of lower ratio of EG/PET, the final product now consists of higher molecular weight of oligomers rather than monomer, dimer, and trimer.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1991.070420603
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  • 7
    Electronic Resource
    Electronic Resource
    Polymer conformation based on correlated walk model (1980)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 18 (1980), S. 175-176 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1980.180180117
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  • 8
    Electronic Resource
    Electronic Resource
    Rebuttal to “comments on ‘some evidence against the existence of the liquid-liquid transition. III. The evaluation of the TLL event by differential scanning calorimetry’ ” (1985)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 23 (1985), S. 13-19 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: It is proposed here that readily observable viscous deformation is the common underlying phenomenon which is reflected in several kinds of evidence advanced for the existence of a liquid-liquid transition TLL. These include flow temperature Tf measurements, microscope hotstage coalescence, and differential scanning calorimetry (DSC) measurements. A DSC peak observed at Tg in high-molecular-weight bulk-polymerized poly(methyl methacrylate) is discussed in terms of the presence of conformations of low entropy.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1985.180230102
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  • 9
    Electronic Resource
    Electronic Resource
    Some evidence against the existence of the liquid-liquid transition. III. The evaluation of the Tll event by differential scanning calorimetryCorrected proofs received July 12, 1982 (1982)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 20 (1982), S. 1565-1574 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The liquid-liquid transition Tll has been examined by using differential scanning calorimetry as the tool of measurement. The results presented show that for the case of polystyrene, the Tll event appears to be an artifact caused by the presence of volatile components. Purified samples of polystyrene, polydienes, and poly(1-butene) do not show the Tll transition.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1982.180200905
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  • 10
    Electronic Resource
    Electronic Resource
    Synthesis and properties of copolymers from 2-hydroxyethyl methacrylate-linked nonsteroidal antiinflammatory agents with methacrylic acid (1998)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 36 (1998), S. 1481-1490 
    Details
    ISSN: 0887-624X
    Keywords: ibuprofen ; ketoprofen ; naproxen ; copolymer reactivity ; thermal stability ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Three nonsteroidal antiinflammatory drugs, 2-(4-isobutylphenyl)-propionic acid (ibuprofen), 2-(3-benzoylphenyl)-propionic acid (ketoprofen), and 2-(6-methoxy-2-naphthyl)-propionic acid (naproxen), were covalently linked with 2-hydroxyethyl methacrylate (HEMA). The drug-linked HEMA (M1) (ibuprofen-linked HEMA abbreviated as HI; ketoprofen-linked HEMA as HK, and naproxen-linked HEMA as HN), were respectively copolymerized with methacrylic acid (M2), MA, to obtain macromolecular prodrugs. The compositions of the copolymers were determined by means of a 1H-NMR spectroscopy and monomer reactivity ratios were estimated using the Kelen-Tüdös linear differential equation. The reactivity ratios are: r1 = 0.101 ± 0.012, r2 = 1.071 ± 0.065 for HI-MA; r1 = 0.344 ± 0.066, r2 = 0.966 ± 0.032 for HN-MA, and r1 = 0.650 ± 0.182, r2 = 1.032 ± 0.106 for HK-MA, respectively. The monomer reactivity toward to MA radical estimated from 1/r2 values is almost same for all three monomers (1/r2 ∼ 1). The glass transition temperatures of three drug-linked homopolymers go hand in hand with the steric hindrance of three drugs, i.e., ketoprofen 〉 naproxen ≫ ibuprofen calculated the minimum energy by computer molecular modeling. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 1481-1490, 1998
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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