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  • 1
    ISSN: 0887-6266
    Keywords: morphology ; annealing ; UHMWPE gel-film, IR spectral difference ; x-ray diffraction ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: X-ray diffraction of the UHMWPE gel-films has shown that high heating rate annealing of the films causes deformation of the crystallites. The apparent crystal sizes change with the annealing temperature (Ta). With Ta below 110°C, the dimensions of the crystallites in c-axis (Lc) increase associated with the decreasing in a-axis (La) and b-axis (Lb), but the changes are small because of the higher energy barrier. When Ta is raised to 138°C, Lc is nearly doubled its value at 60°C whereas Lb increases and La remains unchanged. IR spectral subtraction was applied to reveal the morphological changes of the gel-films upon annealing. It has been found that bands of the same type of conformation have different sensitivities subject to the thermal treatment at different annealing temperatures. The results can be understood by assuming the changing process being completed through chain segments sliding along the (020) sectors. © 1995 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 62 (1996), S. 1987-1991 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In this work, polyacrylonitrile (PAN)-based activated carbon fibers (ACFs) were developed by the common processes of stabilization, carbonization, and steam activation. Those fibers were successively subjected to heat treatment in a vacuum at high temperature and reactivation in steam. The changes in specific surface area and surface chemical characteristics were studied. The vaccum treatment reduced the surface area dramatically, while the surface nitrogen decreased after activation in steam and the surface oxygen was lowered upon the vaccum treatment. By curve-fitting the X-ray photoelectron spectroscopy (XPS) of C1s, O1s, and N1s, it was shown that the forms and compositions of the oxygen-containing functionalities seemed not to be affected significantly by the above-mentioned heat-treat-ment processes, whereas the nitrogen-containing functionalities showed some changes with these treatments. © 1996 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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