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  • 1
    Electronic Resource
    Electronic Resource
    Transport of a gas through asymmetric polysulfone membranes with deposited plasma-polymerized thin layer (1990)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 41 (1990), S. 2427-2436 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A plasma-polymerized thin layer was deposited on the top surface of the skin layer of the asymmetric polysulfone (PSF) membrane to plug ultrafine pores passing through it. Trifluoromethane was used as the monomer gas of plasma polymerization. The steady-state permeation rates for oxygen and nitrogen through the asymmetric PSF membranes with the plasma modification were measured to evaluate the permselectivity and permeability. If ultrafine pores passing through the asymmetric membrane can be plugged by the plasma-polymerized thin layer, the separation factor of oxygen relative to nitrogen can be increased with the permeation rate coefficient of oxygen still kept large. This condition was met when the vaporization time of the cast solution during the preparation of an asymmetric membrane ranged from 10 to 120 s and the plasma polymerization time ranged from 15 to 30 min.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1990.070410942
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Viscosity of concentrated styrene solutions of polystyrene (1968)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 12 (1968), S. 9-11 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Viscosities of concentrated solutions of polystyrene of different intrinsic viscosities were measured at varying polymer concentration and temperature. By modifying Martin's equation, an empirical equation correlating the viscosity of the solution as a function of the polymer concentration, the intrinsic viscosity of the polymer, and temperature was obtained.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1968.070120102
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Polymerization in submonolayers of styrene monomer adsorbed from its vapor phase (1988)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 26 (1988), S. 1519-1527 
    Details
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The surface coverage of porous glass (PD = 500 Å) by styrene adsorbed from its vapor (0.1-6 torr) was studied in a vacuum electrobalance. The adsorption isotherm of the monomer was analyzed by the BET method, and a full monolayer coverage was found to form at a relative pressure of 0.11, weighing 6 mg per gram of glass. Polymerization in submonolayers of adsorbed styrene was initiated by thermal decomposition of predeposited BPO and found to continue until all initiator decomposed, sample cooled, or vapor removed, hence allowing a controlled film thickness. The films were extracted in THF and analyzed by computerized GPC. Molecular weights were in the range 18000-69000. These were related to the rates of polymerization by the usual statistical correlations.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/polb.1988.090260713
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    Paper (German National Licenses)
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