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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 25 (1974), S. 166-171 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Structure and properties of special metal coatings applied by thermal sprayingThermal spraying of metals of groups IVa, Va and VI a is difficult because of the fast oxidation of these metals (Ti, Zr, Ta, Nb, W, Mo). It is consequently of vital importance that the atmosphere be oxygen-free, it is that the spray process is carried in an inert atmosphere. In view of the high cost involved in such a system it is necessary to provide for recirculation of an inert gas. The coatings obtained in pure argon are characterized by very high adhesion strength which is due to diffusion phenomena at the base metal/coating interphase. This diffusion takes place at high velocities and the thickness of the diffusion layer depends from the state of perturbation of the superficial zone of the base metal (e. g. perturbation due to sand blasting) and of the perturbation of the atomic structure of the liquid particles at the high temperature. Titanium coatings thus obtained are completely free from inclusions when obrained in argon, while they are severly embrittled when applied under nitrogen. The properties of coatings from all the metals considered (Ti, Zr, Mo, Nb, Ti6A14V) are perfectly comparable to those of the solid metals.
    Notes: Thermisches Spritzen von Metallen der Gruppen 1 Va, Va und VIa ist wegen der leichten Oxidierbarkeit dieser Metalle (Ti, Zr, Ta, Nb, W und Mo) schwierig. Infolgedessen muß die Atmosphäre sauerstoffrei sein, d. h. man muß in inerter Atmosphäre spritzen. Da hierbei die Kosten ziemlich hoch liegen, muß das Schutzgas in Umlauf geführt werden. Die beim Spritzen in reinem Argon erhaltenen Überzüge besitzen sehr hohe Haftfestigkeit, da es zwischen Grundmetall und Überzug zu Diffusionsvorgängen in der Grenzschicht kommt. Diese Diffusion erfolgt mit sehr hoher Geschwindigkeit; die Dicke der Diffusionsschicht ist abhängig vom Störungszustand der Oberflächenzone des Grundmetalls (Störungen hervorgerufen durch Sandstrahlen z. B.) und von der Störung tur der flüssigen Metallteilchen infolge der hohen Temperatur. Die nach den Schutzgas- verfahren erhaltenen Titanüberzüge sind beim Spritzen in Argon vollkommen frei von Ein- flü,ssen, wahrend beim Spritzen unter Stickstoff starke Versprödung auftritt. Bei allen verwendeten Metallen (Ti, Zr, Mo, Nb, Ti6AI4 V) sind die Überzüge mit den massiven Metal- len vergleichbar.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 15 (1964), S. 533-536 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Atmospheric corrosion of some important systems of base metals and metallic coatingsA corrosion process can be electrochemically represented if it is of  -  electrolytic type, i.e. if it 1takes place in an aqueous solution and2is accompanied by at least one cathodic reduction reaction. These conditions are present in the atmosphere. Depending on temperature and air humidity, the atmosphere contains up to 50 grams of water vapour pr. cubic metre which, under certain conditions, forms the aqueous solution, and it contains, as an oxidant, oxygen which supplies the cathodic reduction reaction. The atmospheric corrosion of a metal can thus be represented by an oxygen corrosion of the metallsolution system, with the aid of the electrochemical presentation of practical corrosion problems, it is possible to obtain data concerning of avoiding or corrosion as well as predictions of the corrosion performance to be expected.
    Notes: Ein Korrosionsvorgang kann elektrochemisch dargestellt werden, wenn er elektrolytischer Art ist, d. h. 1wenn er in einer wäßrigen Lösung abläuft und2wenn mindestens eine kathodische Reduktionsreaktion vorliegt.In der Atmosphäre sind diese Korrosionsvoraussetzungen vorhanden: Sie enthält je nach Temperatur und Luftfeuchte bis zu 50 glm3 Wasserdampf, der unter bestimmten Bedingungen die wäßrige Lösung bildet, und sie enthält das Oxydationsmittel Sauerstoff, der die kathodische Reduktionsreaktion liefert. Die atmosphärische Korrosion eines Metalls kann somit durch eine Sauerstoffkorrosion des Systems Metall Lösung wiedergegeben werden. Aus der elektrochemischen Darstellungsweise praktischer Korrosionsprobleme lassen sich Aussagen über Möglichkeiten zur Vermeidung bzw. Verzögerung der Korrosion sowie Voraussagen über das zu erwartende Korrosionsverhalten gewinnen.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 36 (1974), S. 181-187 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Rheological measurements with polyvinylacetate in dioxane are described and evaluated according to the principles of structure rheology. For the network solution, a concentration independent mass of network strand Me of 2,5 · 105 is found, and an equivalent chain element for c = 0 of Å = 37 Å. The penetration of the network is significantly hindered, the hindrance being smaller for higher concentrations.
    Notes: Es werden rheologische Messungen an Polyvinylacetat in Dioxan beschrieben und nach den Konzepten der Strukturrheologie ausgewertet. Demnach ergibt sich für die Netzwerk-Lösung ein konzentrationsunabhängiges Netzbogengewicht Me von 2,5·105 und ein äquivalentes Fadenelement für c=0 von A'=37 Å. Die Durchdringung des Netzwerkes ist deutlich gehemmt; diese Hemmung wird mit steigender Konzentration geringer.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Selectively deuterated intramolecularly crosslinked macromolecules were studied by dynamic 2H NMR spectroscopy. By performing various relaxation experiments detailed information about the molecular mobility of the various components of the polymer chains could be obtained. In particular, the NMR investigations revealed significant effects of molar mass or degree of isomerization on the motional characteristics.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Acta Polymerica 46 (1995), S. 86-86 
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Acta Polymerica 38 (1987), S. 435-439 
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: The swelling of hollow fibres from regenerated cellulose, prepared by the viscose spinning process, was investigated in different media (water, 10% aqueous NaOH, ethanol amine, and dimethyl sulfoxide) by microscopic measurement of the change of outer diameter and fibre wall thickness with time. With ethanol amine and especially with DMSO as the swelling agent, the increase in outer diameter is delayed, while the increase in fibre wall thickness shows no induction period. From the results, a rather dense structure of thc outer layer of the fibre is concluded.
    Notes: An Celluloseregenerathohlseiden, die nach dem Viskoseverfahren hergestellt waren, wurde die Quellung von Außendurchmesser und Wandstärke in Wasser, Natronlauge, Ethanolamin und Dimethylsulfoxid lichtmikroskopisch verfolgt. In Ethanolamin und vor allem in DMSO zeigt sich ein verzögertes Einsetzen der Zunahme des Außendurchmessers, nicht aber der Wandstärke der Fäden. Hieraus wird auf einen dichteren, die Quellung verzögerden Aufbau der Außenschicht des Hohlfadens geschlossen.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 121 (1969), S. 58-69 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: The concept of network solution is tested with polyvinylacetate (Mowilith) in dioxane. For this end, flow curves and log η0 vs. log M diagrams were determined. The molecular parameters as well as the characteristics of the network solution are derived.
    Notes: Das Konzept der Netz-Lösung wird an Polyvinylacetat (Mowilith) in Dioxan geprüft. Dazu werden Fileßkurven und Kinckdiagramme (log η0 vs. log M) aufgenommen und daraus molekulare Parameter und die charakteristika der Netz-Lösung ermittelt.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 4 (1973), S. 76-81 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Thermal spraying. Thermal spraying in comparison with other coating techniques is characterized by a broad variability of base and spraying materials. After a brief description of actually used equipments some coating properties are summarized. Thermally sprayed special metal will become interesting in near future from commercial and technical point of view. With those metals homogeneous coatings can be produced without porosity.
    Notes: Das thermische Spritzen zeichnet sich gegenüber anderen Verfahren zur Oberflächenbeschichtung durch die Vielfältigkeit der verwendbaren Grund- und Spritzwerkstoffe aus. Neben einer Beschreibung gegenwärtig eingesetzter Geräte wird kurz auf den Schichtaufbau eingegangen. Wirtschaftlich und technisch von besonderem Interesse werden in naher Zukunft thermisch gespritzte Schichten aus Sondermetallen sein, die sich unter Schutzgas porenfrei und homogen erzeugen lassen.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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