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  • Polymer and Materials Science  (3)
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  • 1
    Digitale Medien
    Digitale Medien
    Modelling studies of the controlled anionic copolymerization of butadiene and styreneDedicated to Professor Maurice Morton to commemorate the establishment of the Maurice Morton Institute of Polymer Science at the University of Akron. (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Polymer International 33 (1994), S. 151-159 
    Details
    ISSN: 0959-8103
    Schlagwort(e): anionic copolymerization ; modelling studies ; styrene ; butadiene ; polymerization ; Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The anionic polymerization of isoprene with n-butyl lithium and polar modifier such as TMEDA and tripiperdinophosphine oxide were studied and kinetic and reactor models are proposed for these systems. Reactor conversion, molecular weight distribution and polymer glass transition temperature had been calculated from the model and compared favorably to the actual data for various combinations of reactor systems and operating conditions. Simulations of the model can be used to design reactor systems and predict polymer properties of large-scale operations from results of small scale batch reactor runs.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pi.1994.210330205
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  • 2
    Digitale Medien
    Digitale Medien
    Fundamental modeling in anionic polymerization processes (1990)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 39 (1990), S. 2395-2417 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The anionic solution polymerization of butadiene was studied employing both batch and continuous reactor operations with n-butyllithium (n-BuLi) initiator, tetramethylethylenediamine (TMEDA) modifier, and hexane solvent. A model was proposed that described the kinetics as a function of both the fully modified and unmodified regressed rate data. Using the proposed kinetic model, the conversion, vinyl structure, and heterogeneity index of polymers produced for a series of continuous runs were successfully predicted. The model was used to simulate several process configurations.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1990.070391115
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  • 3
    Digitale Medien
    Digitale Medien
    The reaction engineering of the anionic polymerization of isoprene (1993)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 47 (1993), S. 1589-1599 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The anionic solution polymerization of isoprene with n-butyllithium (n-BuLi) initiator and tetramethylethylenediame (TMEDA) modifier or n-butyllithium (n-BuLi)initiator and tripiperidinophosphine (TPPO) modifier was studied and kinetic and reactor models are proposed for both systems. Reactor conversion, molecular weight distribution, and polymer glass transition temperature had been calculated from the model and compared favorably to actual data for various combinations of reactor system and operating conditions. Simulations of the models can be used to design reactor systems, and predict polymer properties of a large-scale operation from results of small-scale batch reactor runs. © 1993 John Wiley & Sons, Inc.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1993.070470907
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