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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 22 (1971), S. 148-157 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Properties and reactions of chromium sulphides as products of the high-temperature corrosion of NiCr2OTiAl (Nimonic 80 A)The sulphide phase on corroded blades of gas turbines (for natural gas and blast furnace gas) has been identified, by means of electron micro-analysis and X-ray diffraction, as CrNi sulphide with variable Ni and Ti content. This sulphide is of the same type as Cr3So4, and the Structure is not affected by the Ti content. At high temperatures, the CrNi(Ti) sulphides undergo transformations in the solide state, giving rise to Cr and Ni sulphides with higher sulphur contents. It has been possible to prove experimentally that the presence of small discs or bars of crNi sulphide amid the NiS was due to the crystallisation of Ni Cr2So4 from a eutectic Ni3S2Ni melt. At temperatures in excess of 750°C, monoclinic Ni0.5Cr2.5S4 is transformed into a hexagonal modification, just as Ni0.5Ti0.3Cr2.2S4.
    Notes: An korrodierten Gasturbinenschaufeln (aus Erdgas- und Gichtgasturbinen) wurde die Sulfidphase mittels Elektronenstrahl-Mikroanalyse und Röntgenbeugung als CrNi-Sulfid mit variablem Ni- und Ti-Gehalt identifiziert. Dies Sulfid ist isotop mit Cr3So4; der Ti-Gehalt verändert die Struktur nicht. Die CrNi(Ti)-Sulfide erleiden bei hohen Temperaturen Umwandlungen im festen Zustand, wobei schwefelreichere Cr-Sulfide und Ni-Sulfide entstehen. Plättchen- und stäbchenförmige CrNi-Sulfide inmitten von NiS sind - wie experimentell nachgewiesen werden konnte - auf Kristallisation von NiCr2S4 aus einer eutektischen Ni3S2-Ni-Schmelze zurückzuführen. Bei Temperaturen 〉 750°C wandelt sich monoklines Ni0,5Cr2,5S4 um in ene hexagonale Modifikation, ebenso wie Ni0,5Ti0,3Cr2,2S4.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 31 (1980), S. 387-393 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Pitting and crevice corrosion of stainless steels in chloride solutionsIn practice stainless steels in chloride containing waters are found to be susceptible to crevice corrosion and pitting. Corrosion tests were carried out on AISI 304 L stainless using a simulated crevice and the compositions of the electrolyte in the crevice determined. Long term potentiostatic tests were used to determine the critical potentials for crevice corrosion (US), for various steels in sodium chloride solutions at different concentrations and temperatures. The steels studied were 22 CrMo V 121, X 22 CrNi 17 and AISI 304 L.Like the critical pitting potential (UL), US was found to have a strong dependence on the chloride content of the external solution. At higher concentrations the two potentials were similar. At lower concentrations the US was lower than UL. The knowledge of these critical potentials together with well known rest potentials for a steel in an electrolyte of known concentration, allows conclusions to be drawn about its susceptibility to pitting and crevice corrosion.The method is suitable also for other passive metals.
    Notes: In der Praxis entstehen bei rostfreien Stählen, die in chloridhaltigem Wasser eingesetzt werden, immer wieder Schäden durch Spaltkorrosion. Es wurden Korrosionsversuche in einem Spaltmodell mit dem Stahl AISI 304 L angestellt und die Zusammensetzung des Spaltelektrolyten bestimmt. Anhand potentiostatischer Langzeitversuche in Natriumchloridlösungen verschiedener Konzentration und Temperatur wurden in einer Spaltkorrosionszelle die kritischen Potentiale für Spaltkorrosion (US) folgender Stähle bestimmt: 22 CrMo V 121, X 22 CrNi 17 und AISI 304 L.Analog zu den kritischen Potentialen für Lochkorrosion (UL) zeigte US eine starke Abhängigkeit vom Chloridgehalt der Außenlösung. Bei hohen Konzentrationen lagen beide Potentiale nahe beisammen, bei tiefen Chloridkonzentrationen war US tiefer als UL. Die Kenntnis der kritischen Potentiale erlaubt, bei bekanntem Ruhepotential UR eines Stahles in einem Elektrolyten bekannter Chloridkonzentration Rückschlüsse auf die Gefährdung durch Loch- und Spaltkorrosion zu ziehen.Die Methode eignet sich auch für andere passivierbare Metalle.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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