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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 8 (1952), S. 457-465 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Light scattering and ultracentrifuge experiments were made on iodinated fibrinogen. The molecular weight was found to be 560,000 and the length 900 A. The experiments on polymerized iodo-fibrinogen indicated that the lateral and end-to-end associations have different pH optima.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 24 (1957), S. 105-123 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Measurements of excited lifetime and of degree of polarization have been combined to yield values for the mean relaxation time of fluorescent conjugates of bovine serum albumin, egg albumin, and lysozyme. Evidence has been presented for the validity of relaxation times thus computed and for the absence of contributions from nonrandomness of fluorescent residue orientation and from internal degrees of rotational freedom.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 65 (1993), S. 1129-1130 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 67 (1995), S. 352-352 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 50 (1978), S. 408-408 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 26 (1995), S. 374-378 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Investigations on erosion protection of carbon-fibre-reinforced thermosetting plasticsA double layer system of polyurethane rubber and a metal foil was described by calculation and experiment. There is a significant increase in erosion resistance of a carbon-fibre-reinforced plastic component by application of this system and the experimental results correlate with theoretical estimations. Among the investigated materials surface layers of titanium and a titanium aluminium alloy respectively possess the best resistance in the range of all angles of incidence. The polyurethane rubber also exhibits a very good erosion behaviour under conditions of normal impact as well as at shallow impact angles at room temperature. So the rubber takes care of a good emergency running quality after a destruction of the metal foil. It was found that the relative erosion rate of the protective metal layer decreases with increasing thickness of the rubber. A thickness of about 0,5-0,7 mm of the protective metal layer is sufficient in practice. The titanium foil should have a thickness of about 100-200 m̈m for the design life because if the metal foil is too weak it will undergo destruction rather fast under laboratory conditions. There is no change of the well-known erosion mechanisms with the formation of walls around the places of normal impacts as well as grooving and machining at shallow impact angles by application of the double layer system. An increase in temparature up to 80 °C doesn't cause any change of the erosion rate of the investigated metal foils in the double layer system but will influence the erosion of the polyurethane rubber alone. The galvanic deposition of nickel is another way for the use of the double layer system especially for components with a complex geometric shape.
    Notes: Das mittels Berechnung und Experiment vorgestellte Doppelschichtsystem aus PUR-Elastomer und Metallfolie erhöht den Erosionswiderstand eines CFK-Bauteils um ein bis zwei Größenordnungen, wobei die experimentellen Ergebnisse mit der theoretischen Abschätzung zur Schutzschicht korrelieren. Unter den Untersuchten Werkstoffen besitzen Oberflächenschichten aus Titan und einer Ti-Al-Legierung die beste Erosionsbeständigkeit über alle Winkelbereiche. Das PUR-Elastomer weist ebenfalls vor allem im Prallstrahlbereich sowie auch im Gleitstrahlbereich bein Raumtemperatur ein sehr gutes Erosionsverhalten auf und garantiert damit gute Notlaufeigenschaften bei einer eventuellen Zerstörung der Metallfolie. Die relative Erosionsrate der Metallschutzschicht verringert sich mit zunehmender Elastomerschichtdicke, wobei ca. 0,5-0,7 mm Schichtdicke praktisch ausreichend sind. Die Titanfolie sollte für die angestrebte Lebensdauer eine Dicke von ca. 100-200 m̈m aufweisen, da zu dünne Metallfolie im Laborversuch relativ schnell zerrüttet wird. Die REM-Aufnahmen der erodierten Deckschichten zeigen, daß sich durch die Doppelschicht PUR-Elastomer/Metallfolie die bekannten Erosionsmechanismen mit Wallbildung um die Einschläge bei 90% und Furchung bzw. Zerspanung bei kleinen Strahlwinkeln nicht verändern. Eine Temperaturerhöhung bis auf 80 °C bewirkte keine veränderung der Erosionsrate der untersuchten Metallfolien im Doppelschichtsystem, jedoch wird die Erosion der PUR-Elastomerschicht beeinflußt. Alternativ aufgebrachte, galvanisch abgeschiedene Nickelschichten ermöglichen die Nutzung des Doppelschichtsystems auch für geometrisch komplizierte Bauteile.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 24 (1985), S. 547-563 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Derivatives of calmodulin have been prepared in which tyrosine-99 and tyrosine-138 have been converted to their aminotyrosine derivatives. Significant changes in microenvironment occur in the presence of Ca2+. Both groups have a significant degree of mobility with respect to the protein matrix; this is Ca2+ dependent.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 18 (1979), S. 1261-1276 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Fluorescent conjugates of hemoglobin A, its isolated β-chain, and the apo-derivative of the β-chain have been prepared in which the β-93 sulfhydryl was conjugated with 1,5-AEDANS. Radiationless enery transfer to the heme group results in a major decrease in fluorescence intensity and decay time. Measurements of the time decay of fluorescence anisotropy, employing single-photon counting, indicate that the apparent rotational correlation time is, in each case, substantially reduced from the value expected for a rigid molecule of the same molecular weight. This observation raises the possibility that internal degrees of rotational freedom exist.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 21 (1982), S. 1411-1425 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Phosphorylase kinase contains four approximately equivalent binding sites for 1-anilinonaphthalene-8-sulfonate (1,8-ANS). Measurements of the time decay of fluorescence anisotropy have failed to give any indication of internal degrees of rotational freedom involving a significant portion of the tertiary structure. In the presence of 1 mM Ca2+, calmodulin binds one molecule of 1,8-ANS. No binding occurs in the absence of Ca2+. The binding is strongly temperature-dependent, a decrease in binding occurring with increasing temperature. Determinations of the time decay of fluorescence anisotropy indicate the presence of internal rotations, which become more important with increasing temperature. Complex formation between phosphorylase kinase and calmodulin reduces the binding of 1,8-ANS.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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