ISSN:
1572-8951
Keywords:
Polyoxoalkoxymetalates
;
polyoxovanadates
;
polyoxomolybdates
;
metal alkoxides
;
clusters
;
tetrametalate core
;
hexametalate core
;
decametalate core
;
hydrothermal synthesis
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract While the chemistry of polyoxoanions has been extensively studied, the related polyoxoalkoxide clusters remain relatively unexplored. Recent investigations into the coordination chemistry of polyoxoanions with alkoxide ligands demonstrate the existence of a rich structural chemistry which is now emerging. The introduction of alkoxide ligands into polyoxoanion cores significantly expands the structural diversity of the cluster types and allows the isolation not only of fully-oxidized cores with all metal centers possessing d0 electronic configurations but of fully-reduced and mixed valence systems.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00999626
Permalink
