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Template-directed oligomerization of 3-isoadenosine 5′-phosphate (1988)

Hill, Aubrey R. ; Kumar, Shiv ; Leonard, Nelson J. ; [et al.]

Springer

Journal of molecular evolution 27 (1988), S. 91-95

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ISSN: 1432-1432

Keywords: 3-Isoadenosine 5′-phosphate ; Template-directed condensation ; Poly(iA) ; X-ray ; Hoogsteen base pairing ; Prebiotic

Source: Springer Online Journal Archives 1860-2000

Topics: Biology

Notes: Summary Template-directed oligomerization of an activated derivative of 3-isoadenosine 5′-phosphate (piA) on polyuridylic acid [poly(U)] was studied. The reaction of ImpiA is more efficient than the corresponding reaction of ImpA, and produces 3′–5′-linked oligomers while the reaction of ImpA gives only 2′–5′-linked oligomers. The base pairing between piA and poly(U) in this system is probably of the Hoogsteen type (involving the 6-amino group and N7 of 3-isoadenosine) rather than of the Watson-Crick type.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF02138366

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