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  • Chemistry  (1)
  • Primary 39B50, 33A70  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Aequationes mathematicae 31 (1986), S. 223-242 
    ISSN: 1420-8903
    Keywords: Primary 39B50, 33A70
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract The interrelation of polylogarithmic functional equations and certain numerical results, known as “ladders”, is discussed, and leads to a consideration of three new, single-variable functional equations at the second order. Two of these families each contain six leading terms whose interrelationship constitutes a constraint on the integration process, but the third has only a single leading term with no such constraints. It is shown how this functional equation can be integrated to the third order, and the process reduced to an algorithm — actually a sequence of instructions — for incorporation into a computer program for symbolic manipulation. The procedure utilizes results from Kummer's equations to cancel out, in sequence, terms which do not vanish, or do vanish, with the variablez. Arguments are all of the form ±z p (1−z) q (1+z) r , and the process is “algebraicized” by using a (p,q,r,s) notation (withs=±1) to represent such terms. Application of the procedure leads to an integration to the fourth and fifth orders, the latter exhibiting 55 transcendental terms. The first step for the transition to the sixth order can also be achieved but the subsequent steps are frustrated by the restricted forms that the Kummer equations take at the fifth order — it is not possible to create the needed equations in a form which vanishes withz; this corresponding to the elimination of the ζ(5) constant in the extension of the numerically determined ladders to the sixth and higher orders. The existence of the higher-order ladders strongly suggests functional equations af these orders, but the present process has not yet been successful in finding them. The new equations have, however, produced ladders that were inaccessible from Kummer's equations, and had heretofore been only obtainable numerically, up to the fifth order. The method which was developed should be capable of generalization to other systems of equations characterized by the appearance of arguments with recurrent factors. Some new feature, however, will need to be determined before the barrier to the sixth order can be breached.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 586 (1990), S. 19-24 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Adducts and Salts Formed by Sulphurchlorides with AlCl3The instability of the adduct 2 S2Cl2 · AlCl3 is proven. S2Cl2 · AlCl3 and S2Cl2 · 2 AlCl3 reported in the literature could not be found under proper conditions, their formation seems improbable. The product 2 SCl4 · 3 AlCl3, obtained by the reaction of [SCl3]+[AlCl4]- with elementary sulphur, is characterized as a double salt [SCl3]2+[AlCl4]- [Al2Cl7]-. The [Al2Cl7]- anion is also found as an intermediate during the thermal decomposition of [SCl3]+[AlCl4]- and when metallic aluminium reacts directly with S2Cl2. For SCl2 · AlCl3, the ionic character with a chlorsulfenium cation [SCl]+ is proven spectroscopically.
    Notes: Die Instabilität des Addukts 2 S2Cl2 · AlCl3 wird nachgewiesen. Die in der Literatur genannten Verbindungen S2Cl2 · AlCl3 und S2Cl2 · 2 AlCl3 konnten unter den angegebenen Bedingungen nicht gefunden werden, ihre Bildung ist unwahrscheinlich. Ein durch die Umsetzung von [SCl3]+[AlCl4]- mit elementarem Schwefel in CCl4 erhaltenes Produkt der Zusammensetzung 2 SCl4 · 3 AlCl3 wird als Doppelsalz [SCl3]2+[AlCl4]- und beider Umsetzung von metallischem Al mit S2. Der ionogene Charakter des SCl · ALCl3, mit einem Chlorsulfenium-Kation [SCl]+ wird spektroskopisch nachgewiesen.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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