ISSN:
1572-9028
Keywords:
Pt catalysts
;
SMSI
;
TiO2-supported Pt
;
Pt/TiO2
;
Pt/SiO2
;
Pt/Al2O3
;
hydrogenation of: crotonaldehyde
;
benzaldehyde
;
phenylacetaldehyde
;
acetophenone
;
acetone
;
butyraldehyde
;
benzyl alcohol
;
1–phenylethanol
;
acetylcyclohexane
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The vapor–phase hydrogenation of a group of aldehydes and ketones which contain unsaturated C=C bonds has been studied over a family of supported Pt catalysts. Turnover frequencies, activation energies and reaction orders for crotonaldehyde, benzaldehyde, phenylacetaldehyde and acetophenone are provided and compared to those for butyraldehyde, benzyl alcohol, 1–phenylethanol, acetylcyclohexane and acetone. Metal–support interactions (MSI) induced in Pt/TiO2 not only enhance specific activity but also markedly shift selectivity because hydrogenation of the carbonyl bond is favored. The retention of high selectivity to the intermediate unsaturated alcohols shows that adsorption properties, as well as kinetic parameters, are altered. A model is discussed which describes the sites responsible for this behavior.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1019156726267
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