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15N NMR study of the linkage isomerism of pentaammine(glycinato)rhodium(III) (1991)

Appleton, Trevor G. ; Cox, Matthew R.

Chichester : Wiley-Blackwell

Organic Magnetic Resonance 29 (1991), S. S80

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ISSN: 0749-1581

Keywords: Rhodium ; Pentaammine ; Glycinato ; 15N NMR ; Linkage isomers ; Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Refluxing a solution of [Rh(NH3)5(gly-O)]2+ at pH 10 produces [Rh(NH3)5(gly-N)]2+ (glyH = glycine, +NH3CH2CO2-). 15N NMR spectra of reaction mixtures obtained with either 14N or 15N isotopes present in the ammine or glycinate ligands are consistent only with the O- to N-isomerization reaction being intramolecular. The analogous β-alaninate complex does not isomerize under similar conditions.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/mrc.1260291315

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